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In physics and general relativity, gravitational redshift (known as Einstein shift in older literature) [1] [2] is the phenomenon that electromagnetic waves or photons travelling out of a gravitational well lose energy. This loss of energy corresponds to a decrease in the wave frequency and increase in the wavelength, known more generally as a ...
In physics, a redshift is an increase in the wavelength, and corresponding decrease in the frequency and photon energy, of electromagnetic radiation (such as light).The opposite change, a decrease in wavelength and increase in frequency and energy, is known as a blueshift, or negative redshift.
An auxochrome is known as a functional group that produces a bathochromic shift, also known as red shift because it increases the wavelength of absorption, therefore moving closer to infrared light. Woodward−Fieser rules estimate the shift in wavelength of maximum absorption for several auxochromes attached to a conjugated system in an ...
The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to electrons making a transition from a high energy state to a lower energy state. The photon energy of the emitted photons is equal to the energy difference between the two states. There are many possible ...
The color of chemicals is a physical property of chemicals that in most cases comes from the excitation of electrons due to an absorption of energy performed by the chemical. The study of chemical structure by means of energy absorption and release is generally referred to as spectroscopy.
In spectroscopy, bathochromic shift (from Greek βαθύς (bathys) 'deep' and χρῶμα (chrōma) 'color'; hence less common alternate spelling "bathychromic") is a change of spectral band position in the absorption, reflectance, transmittance, or emission spectrum of a molecule to a longer wavelength (lower frequency). [1]
An overview of absorption of electromagnetic radiation.This example shows the general principle using visible light as a specific example. A white light source—emitting light of multiple wavelengths—is focused on a sample (the pairs of complementary colors are indicated by the yellow dotted lines).
Positive solvatochromism corresponds to a bathochromic shift (or red shift) with increasing solvent polarity. An example of positive solvatochromism is provided by 4,4'-bis(dimethylamino)fuchsone, which is orange in toluene, red in acetone. The main value of the concept of solvatochromism is the context it provides to predict colors of solutions.