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An often cited description of the sawtooth relaxation is that by Kadomtsev. [2] The Kadomtsev model uses a resistive magnetohydrodynamic (MHD) description of the plasma. If the amplitude of the current density in the plasma core is high enough so that the central safety factor is below unity, a = linear eigenmode will be unstable, where is the poloidal mode number.
Larry E. Overman's synthesis of laurenyne utilizes a one-pot oxidation with pyridinium chlorochromate followed by a Saegusa oxidation, tolerating the presence of a halogen and a sulfonate. [13] Overman synthesis of laurenyne. The synthesis of sambutoxin reported by David Williams uses a novel Saegusa–Ito oxidation involving an unprotected ...
The sawtooth wave (or saw wave) is a kind of non-sinusoidal waveform. It is so named based on its resemblance to the teeth of a plain-toothed saw with a zero rake angle. A single sawtooth, or an intermittently triggered sawtooth, is called a ramp waveform. The convention is that a sawtooth wave ramps upward and then sharply drops.
The Sharpless epoxidation is viable with a large range of primary and secondary alkenic alcohols. Furthermore, with the exception noted above, a given dialkyl tartrate will preferentially add to the same face independent of the substitution on the alkene.To demonstrate the synthetic utility of the Sharpless epoxidation, the Sharpless group created synthetic intermediates of various natural ...
The Seyferth–Gilbert homologation is a chemical reaction of an aryl ketone 1 (or aldehyde) with dimethyl (diazomethyl)phosphonate 2 and potassium tert-butoxide to give substituted alkynes 3. [ 1 ] [ 2 ] Dimethyl (diazomethyl)phosphonate 2 is often called the Seyferth–Gilbert reagent .
This requires mixing the compounds in a reaction vessel, such as a chemical reactor or a simple round-bottom flask. Many reactions require some form of processing ("work-up") or purification procedure to isolate the final product. [1] The amount produced by chemical synthesis is known as the reaction yield.
The Hajos–Parrish–Eder–Sauer–Wiechert and Barbas-List [1] reactions in organic chemistry are a family of proline-catalysed asymmetric aldol reactions.. In the 1970s, two research groups discovered (and published) almost simultaneously their discoveries of two related intramolecular reactions: Zoltan Hajos and David Parrish at Hoffmann-La Roche [2] [3] and Rudolf Wiechert et al at ...
[4] [5] The reaction has since been extended to the synthesis of β-keto esters from the condensation between aldehydes and diazo esters. [6] The general reaction scheme is as follows: General Scheme for Buchner Reaction. The reaction yields two possible carbonyl compounds (I and II) along with an epoxide (III). The ratio of the products is ...