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A mixture of ammonia gas and water vapor is introduced into a reactor that contains a saturated solution of ammonium sulfate and about 2% to 4% of free sulfuric acid at 60 °C. Concentrated sulfuric acid is added to keep the solution acidic, and to retain its level of free acid. The heat of reaction keeps reactor temperature at 60 °C.
Ammonium sulfite can be prepared by the reaction of ammonia with sulfur dioxide in aqueous solution: . 2 NH 3 + SO 2 + H 2 O → (NH 4) 2 SO 3. Ammonium sulfite is produced in gas scrubbers, now obsolete, consisting of ammonium hydroxide to remove sulfur dioxide from emissions from power plants.
It is the salt derived from the ammonium cation and the hydrosulfide anion.The salt exists as colourless, water-soluble, micaceous crystals. On Earth the compound is encountered mainly as a solution, not as the solid, but [NH 4]SH ice is believed to be a substantial component of the cloud decks of the gas-giant planets Jupiter and Saturn, with sulfur produced by its photolysis responsible for ...
Ammonium iron(II) sulfate, or Mohr's salt, is the inorganic compound with the formula (NH 4) 2 SO 4 ·Fe(SO 4)·6H 2 O.Containing two different cations, Fe 2+ and NH + 4, it is classified as a double salt of ferrous sulfate and ammonium sulfate.
Ammonium sulfate is an inorganic salt with a high solubility that disassociates into ammonium (NH + 4) and sulfate (SO 2− 4) in aqueous solutions. [1] Ammonium sulfate is especially useful as a precipitant because it is highly soluble, stabilizes protein structure, has a relatively low density, is readily available, and is relatively inexpensive.
It is commonly collected as a byproduct of the "acetone cyanohydrin route" to the commodity chemical methyl methacrylate. [1]It can also be obtained by hydrolysis of sulfamic acid in aqueous solution, which produces the salt in high purity:
The ammonium ion is mildly acidic, reacting with Brønsted bases to return to the uncharged ammonia molecule: [NH 4] + + B − → HB + NH 3. Thus, the treatment of concentrated solutions of ammonium salts with a strong base gives ammonia. When ammonia is dissolved in water, a tiny amount of it converts to ammonium ions: H 2 O + NH 3 ⇌ OH − ...
Ammonium persulfate is prepared by electrolysis of a cold concentrated solution of either ammonium sulfate or ammonium bisulfate in sulfuric acid at a high current density. [2] [3] The method was first described by Hugh Marshall.