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Manganese(IV) oxide (manganese dioxide, MnO 2) is used as a reagent in organic chemistry for the oxidation of benzylic alcohols (where the hydroxyl group is adjacent to an aromatic ring). Manganese dioxide has been used since antiquity to oxidize and neutralize the greenish tinge in glass from trace amounts of iron contamination. [ 45 ]
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Manganese is a chemical element with the symbol Mn and atomic number of 25. It is found as the free element in nature (often in combination with iron), and in many minerals. The free element is a metal with important industrial metal alloy uses. Manganese ions are variously colored, and are used industrially as pigments and as
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Manganese precipitates in soils in the form of manganese-iron oxide minerals, which promote nutrient and organic matter accumulation due to their high surface area. Manganese is the tenth most abundant metal in the Earth's crust, making up approximately 0.1% of the total composition, or about 0.019 mol kg −1 , which is found mostly in the ...
Organomanganese chemistry is the chemistry of organometallic compounds containing a carbon to manganese chemical bond.In a 2009 review, Cahiez et al. argued that as manganese is cheap and benign (only iron performs better in these aspects), organomanganese compounds have potential as chemical reagents, although currently they are not widely used as such despite extensive research.
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