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Copper(II) carbonate or cupric carbonate is a chemical compound with formula CuCO 3. At ambient temperatures, it is an ionic solid (a salt) consisting of copper(II) cations Cu 2+ and carbonate anions CO 2− 3. This compound is rarely encountered because it is difficult to prepare [2] and readily reacts with water moisture from the air.
Basic copper carbonate is a chemical compound, more properly called copper(II) carbonate hydroxide. It can be classified as a coordination polymer or a salt. It consists of copper(II) bonded to carbonate and hydroxide with formula Cu 2 (CO 3)(OH) 2. It is a green solid that occurs in nature as the mineral malachite.
Copper is a chemical element with the symbol Cu (from Latin: cuprum) and the atomic number of 29. It is easily recognisable, due to its distinct red-orange color.Copper also has a range of different organic and inorganic salts, having varying oxidation states ranging from (0,I) to (III).
In aqueous solution, copper(II) exists as [Cu(H 2 O) 6] 2+. This complex exhibits the fastest water exchange rate (speed of water ligands attaching and detaching) for any transition metal aquo complex. Adding aqueous sodium hydroxide causes the precipitation of light blue solid copper(II) hydroxide. A simplified equation is:
Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C ... Copper(II) carbonate: CuCO 3: 1.462×10 −4: Copper(II) chlorate: Cu(ClO 3 ...
In aqueous solution, copper(II) exists as [Cu(H 2 O) 6] 2+. This complex exhibits the fastest water exchange rate (speed of water ligands attaching and detaching) for any transition metal aquo complex. Adding aqueous sodium hydroxide causes the precipitation of light blue solid copper(II) hydroxide. A simplified equation is:
Basic copper carbonate (the "copper carbonate" of commerce), actually a copper carbonate hydroxide; which may be either Cu 2 CO 3 (OH) 2: the green mineral malachite, verdigris, the pigment "green verditer" or "mountain green" Cu 3 (CO 3) 2 (OH) 2: the blue mineral azurite, and the pigment "blue verditer" or "mountain blue" Lapis armenus, a ...
Azurite has the formula Cu 3 (CO 3) 2 (OH) 2, with the copper(II) cations linked to two different anions, carbonate and hydroxide. It is one of two relatively common basic copper(II) carbonate minerals, the other being bright green malachite. Aurichalcite is a rare basic carbonate of copper and zinc. [8]