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There are three sets of Indium halides, the trihalides, the monohalides, and several intermediate halides. In the monohalides the oxidation state of indium is +1 and their proper names are indium(I) fluoride, indium(I) chloride, indium(I) bromide and indium(I) iodide. The intermediate halides contain indium with oxidation states, +1, +2 and +3.
Indium(III) chloride is the chemical compound with the formula In Cl 3 which forms a tetrahydrate. This salt is a white, flaky solid with applications in organic synthesis as a Lewis acid . It is also the most available soluble derivative of indium. [ 2 ]
Indium(I) compounds are not common. The chloride, bromide, and iodide are deeply colored, unlike the parent trihalides from which they are prepared. The fluoride is known only as an unstable gas. [42] Indium(I) oxide black powder is produced when indium(III) oxide decomposes upon heating to 700 °C. [38]
Group 15 consists of the elements nitrogen (N), phosphorus (P), arsenic (As), antimony (Sb), bismuth (Bi), and moscovium (Mc). Since 1988, it has been called Group 15 by the IUPAC . Before that, in America it was called Group V A , owing to a text by H. C. Deming and the Sargent-Welch Scientific Company , while in Europe it was called Group V B ...
To obtain the trialkyl derivatives, alkylation of indium trihalides with organolithium reagents is typical. [4] OrganoIn(III) compounds are also prepared by treating In metal with alkyl halides. This reaction gives mixed organoindium halides. Illustrative is the reaction of allyl bromide with a THF suspension of indium.
Indium trichloride (indium(III) chloride), InCl 3 This page was last edited on 21 September 2024, at 17:06 (UTC). Text is available under the Creative Commons ...
Phthalocyanine green is derived from phthalocyanine blue by chlorination in the presence of aluminium trichloride. The stoichiometry for the complete chlorination is shown: [1] Cu(C 32 H 16 N 8) + 16 Cl 2 → Cu(C 32 N 8 Cl 16) + 16 HCl. In practice, this pigment is a mixture of isomers and degrees of chlorination.
Solubility tables; Substance Formula 0 °C 10 °C 15 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Actinium(III) hydroxide