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In chemistry, a superoxide is a compound that contains the superoxide ion, which has the chemical formula O − 2. [1] The systematic name of the anion is dioxide(1−).The reactive oxygen ion superoxide is particularly important as the product of the one-electron reduction of dioxygen O 2, which occurs widely in nature. [2]
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Superoxides are a class of compounds that are very similar to peroxides, but with just one unpaired electron for each pair of oxygen atoms (O − 2). [6] These compounds form by oxidation of alkali metals with larger ionic radii (K, Rb, Cs). For example, potassium superoxide (KO 2) is an orange-yellow solid formed when potassium reacts with oxygen.
superoxide (O − 2) is produced by reduction of O 2. [4] Several grams are produced per day in the human body within the mitochondria. [5] O 2 + e − → O − 2. Competing with its formation, superoxide is destroyed by the action of superoxide dismutases, enzymes that catalyze its disproportionation: 2 O − 2 + 2H + → O 2 + H 2 O 2
The superoxide anion, • O − 2, and the hydroperoxyl radical exist in equilibrium in aqueous solution: • O − 2 + H 2 O ⇌ HO • 2 + HO −. The pK a of HO 2 is 4.88. Therefore, about 0.3% of any superoxide present in the cytosol of a typical cell is in the protonated form. [4] It oxidizes nitric oxide to nitrogen dioxide: [2] • NO ...
Specifically, an increase in superoxide affects aging whereas a decrease in nitric oxide formation, or its bioavailability, does the same. [ 25 ] Antioxidants are helpful in reducing and preventing damage from free radical reactions because of their ability to donate electrons which neutralize the radical without forming another.
Chemical substances that can catalyze the formation of superoxide Pages in category "Superoxide generating substances" The following 5 pages are in this category, out of 5 total.
Caesium superoxide is a chemical compound with the chemical formula CsO 2. It consists of caesium cations Cs + and superoxide anions O − 2 . It is an orange solid.