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Alkanes are broken apart at high temperatures, often in the presence of a zeolite catalyst, to produce a mixture of primarily aliphatic alkenes and lower molecular weight alkanes. The mixture is feedstock and temperature dependent, and separated by fractional distillation. This is mainly used for the manufacture of small alkenes (up to six ...
Alkanes have the general chemical formula C n H 2n+2. The alkanes range in complexity from the simplest case of methane (CH 4), where n = 1 (sometimes called the parent molecule), to arbitrarily large and complex molecules, like pentacontane (C 50 H 102) or 6-ethyl-2-methyl-5-(1-methylethyl) octane, an isomer of tetradecane (C 14 H 30).
The bonding between alkenes and transition metals is described by the Dewar–Chatt–Duncanson model, which involves donation of electrons in the pi-orbital on the alkene to empty orbitals on the metal. This interaction is reinforced by back bonding that entails sharing of electrons in other metal orbitals into the empty pi-antibonding level ...
The predominant use of hydrocarbons is as a combustible fuel source. Methane is the predominant component of natural gas. C 6 through C 10 alkanes, alkenes, cycloalkanes, and aromatic hydrocarbons are the main components of gasoline, naphtha, jet fuel, and specialized industrial solvent mixtures.
Higher alkanes are naturally present in crude oil and can be obtained via fractional distillation.Saturated fatty acids decarboxylate to higher alkanes. Long olefins can be hydrogenated to yield higher alkanes. n-alkanes can be isolated via the formation of urea clathrates.They can also be synthesized through Kolbe electrolysis or other coupling reactions like the Wurtz reaction.
In organic chemistry, terminal alkenes (alpha-olefins, α-olefins, or 1-alkenes) are a family of organic compounds which are alkenes (also known as olefins) with a chemical formula C x H 2x, distinguished by having a double bond at the primary, alpha (α), or 1-position. [1]
Alkenes cause instability of hydrocarbon fuels. [9] Fluid catalytic cracking is a commonly used process, and a modern oil refinery will typically include a cat cracker, particularly at refineries in the US, due to the high demand for gasoline. [10] [11] [12] The process was first used around 1942 and employs a powdered catalyst. During WWII ...
As depicted in Figure 2, some of the smaller alkanes are then broken and converted into even smaller alkenes and branched alkenes such as the gases ethylene, propylene, butylenes, and isobutylenes. Those olefinic gases are valuable for use as petrochemical feedstocks.