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The Meerwein arylation is an organic reaction involving the addition of an aryl diazonium salt (ArN 2 X) to an electron-poor alkene usually supported by a metal salt. [1] The reaction product is an alkylated arene compound. The reaction is named after Hans Meerwein, one of its inventors who first published it in 1939. Meerwein arylation
Electronegativity is not a uniquely defined property and may depend on the definition. The suggested values are all taken from WebElements as a consistent set. Many of the highly radioactive elements have values that must be predictions or extrapolations, but are unfortunately not marked as such.
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Metals in the middle of the reactivity series, such as iron, will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt, such as iron(II) sulfate: Fe (s) + H 2 SO 4 (l) → FeSO 4 (aq) + H 2 (g) There is some ambiguity at the borderlines between the groups.
In general, electronegativity increases on passing from left to right along a period and decreases on descending a group. Hence, fluorine is the most electronegative of the elements (not counting noble gases), whereas caesium is the least electronegative, at least of those elements for which substantial data is available. [26]
The values below are standard apparent reduction potentials (E°') for electro-biochemical half-reactions measured at 25 °C, 1 atmosphere and a pH of 7 in aqueous solution. [1] [2] The actual physiological potential depends on the ratio of the reduced (Red) and oxidized (Ox) forms according to the Nernst equation and the thermal voltage.
The overall chemical reaction taking place in a cell is made up of two independent half-reactions, which describe chemical changes at the two electrodes. To focus on the reaction at the working electrode , the reference electrode is standardized with constant (buffered or saturated) concentrations of each participant of the redox reaction.
In some reactions between highly reactive metals (usually from Group 1 or Group 2) and highly electronegative halogen gases, or water, the atoms can be ionized by electron transfer, [16] a process thermodynamically understood using the Born–Haber cycle. [17] Salts are formed by salt-forming reactions. A base and an acid, e.g., NH 3 + HCl → ...