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Polyvinyl alcohol (PVOH, PVA, or PVAl) is a water-soluble synthetic polymer. It has the idealized formula [CH 2 CH(OH)] n . It is used in papermaking , textile warp sizing , as a thickener and emulsion stabilizer in polyvinyl acetate (PVAc) adhesive formulations, in a variety of coatings, and 3D printing .
Polyvinyl acetate (PVA) Includes white glue (e.g. Elmer's Glue) and yellow carpenter's glue (Aliphatic resin) (Brands include Titebond and Lepage) Polyvinyl alcohol; Polyvinyl chloride (PVC) Polyvinyl chloride emulsion (PVCE) – a water-miscible emulsion that polymerizes as it cures; Polyvinylpyrrolidone (component of glue sticks) Silicone resins
Vinyl polymers are subject of several structural variations, which greatly expands the range of polymers and their applications. With the exception of polyethylene, vinyl polymers can arise from head-to-tail linking of monomers, head-to-head combined with tail-to-tail, or a mixture of those two patterns. Additionally the substituted carbon center in such polymers is stereogenic (a "chiral center")
Polyethylene glycol–polyvinyl alcohol (PEG-PVA) brand name Kollicoat IR is a multifunctional excipient [1] used as a pill binder as well as a wet binder. A typical formulation is composed of 25% polyethylene glycol (PEG) and 75% polyvinyl alcohol (PVA); where the vinyl alcohol moieties are grafted on a polyethylene glycol backbone.
The term polyol is also attributed to other molecules containing hydroxyl groups. For instance, polyvinyl alcohol is (CH 2 CHOH) n with n hydroxyl groups where n can be in the thousands. Cellulose is a polymer with many hydroxyl groups, but it is not referred to as a polyol.
Ethylene vinyl alcohol (EVOH) is a formal copolymer of ethylene and vinyl alcohol. Because the latter monomer mainly exists as its tautomer acetaldehyde , the copolymer is prepared by polymerization of ethylene and vinyl acetate to give the ethylene vinyl acetate (EVA) copolymer followed by hydrolysis.
Polyvinyl acetate is also the raw material to make other polymers like: Polyvinyl alcohol −[HOCHCH 2 ]−: Polyvinyl acetate is partially or completely hydrolysed to give polyvinyl alcohol. This reversible saponification and esterification reaction was a strong hint for Hermann Staudinger in the formulation of his theory of macromolecules .
Vinyl alcohol, also called ethenol (IUPAC name; not ethanol) or ethylenol, is the simplest enol. With the formula C H 2 CH O H , it is a labile compound that converts to acetaldehyde immediately upon isolation near room temperature. [ 1 ]