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The electron affinity of molecules is a complicated function of their electronic structure. For instance the electron affinity for benzene is negative, as is that of naphthalene, while those of anthracene, phenanthrene and pyrene are positive. In silico experiments show that the electron affinity of hexacyanobenzene surpasses that of fullerene. [5]
Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion.
The energy released when an electron is added to a neutral gaseous atom to form an anion is known as electron affinity. [15] Trend-wise, as one progresses from left to right across a period , the electron affinity will increase as the nuclear charge increases and the atomic size decreases resulting in a more potent force of attraction of the ...
The periodic table, also known as the periodic table of the elements, is an ordered arrangement of the chemical elements into rows ("periods") and columns ("groups"). It is an icon of chemistry and is widely used in physics and other sciences.
where I is the ionization potential and A the electron affinity. This expression implies that the chemical hardness is proportional to the band gap of a chemical system, when a gap exists. The first derivative of the energy with respect to the number of electrons is equal to the chemical potential, μ, of the system,
The broad definition, used generally throughout history, is that chemical affinity is that whereby substances enter into or resist decomposition. [ 2 ] The modern term chemical affinity is a somewhat modified variation of its eighteenth-century precursor "elective affinity" or elective attractions, a term that was used by the 18th century ...
This is a list of chemical elements and their atomic properties, ordered by atomic number (Z).. Since valence electrons are not clearly defined for the d-block and f-block elements, there not being a clear point at which further ionisation becomes unprofitable, a purely formal definition as number of electrons in the outermost shell has been used.
The pnictogens [1] (/ ˈ p n ɪ k t ə dʒ ə n / or / ˈ n ɪ k t ə dʒ ə n /; from Ancient Greek: πνῑ́γω "to choke" and -gen, "generator") are the chemical elements in group 15 of the periodic table. This group is also known as the nitrogen group or nitrogen family.