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The terms anode and cathode are not defined by the voltage polarity of electrodes, but are usually defined by the direction of current through the electrode. An anode usually is the electrode of a device through which conventional current (positive charge) flows into the device from an external circuit, while a cathode usually is the electrode through which conventional current flows out of ...
Various semiconductor diodes. Left: A four-diode bridge rectifier.Next to it is a 1N4148 signal diode.On the far right is a Zener diode.In most diodes, a white or black painted band identifies the cathode into which electrons will flow when the diode is conducting.
A cathode is the electrode from which a conventional current leaves a polarized electrical device such as a lead-acid battery. This definition can be recalled by using the mnemonic CCD for Cathode Current Departs. A conventional current describes the direction in which positive charges move.
The cathode is in many ways the opposite of the anode. The name (also coined by Whewell) comes from the Greek words κάτω (kato), 'downwards' and ὁδός (hodós), 'a way'. It is the positive electrode, meaning the electrons flow from the electrical circuit through the cathode into the non-metallic part of the electrochemical cell.
Zener diodes have a low breakdown voltage. A standard value for breakdown voltage is for instance 5.6 V. This means that the voltage at the cathode cannot be more than about 5.6 V higher than the voltage at the anode (though there is a slight rise with current), because the diode breaks down, and therefore conducts, if the voltage gets any higher.
The metal side acts as the anode, and n-type semiconductor acts as the cathode of the diode; meaning conventional current can flow from the metal side to the semiconductor side, but not in the opposite direction. This Schottky barrier results in both very fast switching and low forward voltage drop.
In photovoltaic mode (zero bias), photocurrent flows into the anode through a short circuit to the cathode. If the circuit is opened or has a load impedance, restricting the photocurrent out of the device, a voltage builds up in the direction that forward biases the diode, that is, anode positive with respect to cathode.
The cathode is coated with a mixture of alkaline earth oxides such as calcium and thorium oxide which reduces its work function so it produces more electrons. The grid is constructed of a helix or screen of thin wires surrounding the cathode. The anode is a cylinder or rectangular box of sheet metal surrounding the grid.