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Aluminium carbide is prepared by direct reaction of aluminium and carbon in an electric arc furnace. [3] 4 Al + 3 C → Al 4 C 3. An alternative reaction begins with alumina, but it is less favorable because of generation of carbon monoxide. 2 Al 2 O 3 + 9 C → Al 4 C 3 + 6 CO. Silicon carbide also reacts with aluminium to yield Al 4 C 3.
In aluminium alloys containing magnesium, magnesium oxides (MgO), cuboids (MgAl 2 O 4-cuboid) and metallurgical spinel (MgAl 2 O 4-spinel) can form. They result from the reaction between magnesium and oxygen in the melt. More of them will form with time and temperature. Spinel can be highly detrimental because of its big size and high hardness.
For some metals, carbothermic reactions do not afford the metal, but instead give the metal carbide. This behavior is observed for titanium, hence the use of the chloride process. Carbides also form upon high temperature treatment of Cr 2 O 3 with carbon. For this reason, aluminium is employed as the reducing agent.
Three examples are aluminium carbide Al 4 C 3, magnesium carbide Mg 2 C [9] and beryllium carbide Be 2 C. Transition metal carbides are not saline: their reaction with water is very slow and is usually neglected.
The aluminium trihalides form many addition compounds or complexes; their Lewis acidic nature makes them useful as catalysts for the Friedel–Crafts reactions. Aluminium trichloride has major industrial uses involving this reaction, such as in the manufacture of anthraquinones and styrene; it is also often used as the precursor for many other ...
Silicon carbide, calcium carbide - used as ladle deoxidizer in steel production; Aluminum dross - also a ladle deoxidizer, used in secondary steelmaking; Calcium - used as a deoxidizer, desulfurizer, or decarbonizer for ferrous and non-ferrous alloys; Titanium - used as a deoxidizer for steels
Industrially, simple aluminium alkyls of the type Al 2 R 6 (R = Me, Et) are prepared in a two-step process beginning with the alkylation of aluminium powder: 2 Al + 3 CH 3 CH 2 Cl → (CH 3 CH 2) 3 Al 2 Cl 3. The reaction resembles the synthesis Grignard reagents. The product, (CH 3 CH 2) 3 Al 2 Cl 3, is called ethylaluminium sesquichloride ...
Aluminium–scandium alloys (AlSc) are aluminum alloys that consist largely of aluminium (Al) and traces of scandium (Sc) as the main alloying elements.In principle, aluminium alloys strengthened with additions of scandium are very similar to traditional nickel-base superalloys in that both are strengthened by coherent, coarsening resistant precipitates with an ordered L1 2 structure.