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The quantum concentration n Q is the particle concentration (i.e. the number of particles per unit volume) of a system where the interparticle distance is equal to the thermal de Broglie wavelength. Quantum effects become appreciable when the particle concentration is greater than or equal to the quantum concentration, which is defined as: [1]
Several sources [2] [12] [3] replace nσ λ with k λ r, where k λ is the absorption coefficient per unit density and r is the density of the gas. The absorption coefficient for spectral flux (a beam of radiation with a single wavelength, [W/m 2 /μm]) differs from the absorption coefficient for spectral intensity [W/sr/m 2 /μm] used in ...
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
Using the carrier concentration equations given above, the mass action law can be stated as = =, where E g is the band gap energy given by E g = E c − E v. The above equation holds true even for lightly doped extrinsic semiconductors as the product n p {\displaystyle np} is independent of doping concentration.
Symbolab is an answer engine [1] that provides step-by-step solutions to mathematical problems in a range of subjects. [2] It was originally developed by Israeli start-up company EqsQuest Ltd., under whom it was released for public use in 2011. In 2020, the company was acquired by American educational technology website Course Hero. [3] [4]
The self-diffusion coefficient of neat water is: 2.299·10 −9 m 2 ·s −1 at 25 °C and 1.261·10 −9 m 2 ·s −1 at 4 °C. [2] Chemical diffusion occurs in a presence of concentration (or chemical potential) gradient and it results in net transport of mass. This is the process described by the diffusion equation.
In order to obtain the equation, the general solution to the Poisson–Boltzmann equation is used and the case of low potentials is dropped. The equation is solved with a dimensionless parameter y ≡ e ψ k B T {\displaystyle y\equiv {\frac {e\psi }{k_{B}T}}} , which is not to be confused with the spatial coordinate symbol, y. [ 4 ]