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A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
The characteristic S-shaped sigmoid curve is obtained with only for integers n ≥ 1. The order of the polynomial in the general smoothstep is 2 n + 1. With n = 1, the slopes or first derivatives of the smoothstep are equal to zero at the left and right edge ( x = 0 and x = 1), where the curve is appended to the constant or saturated levels.
Linear interpolation on a data set (red points) consists of pieces of linear interpolants (blue lines). Linear interpolation on a set of data points (x 0, y 0), (x 1, y 1), ..., (x n, y n) is defined as piecewise linear, resulting from the concatenation of linear segment interpolants between each pair of data points.
A sigmoid function is any mathematical function whose graph has a characteristic S-shaped or sigmoid curve. A common example of a sigmoid function is the logistic function , which is defined by the formula: [ 1 ]
The standard logistic function is the logistic function with parameters =, =, =, which yields = + = + = / / + /.In practice, due to the nature of the exponential function, it is often sufficient to compute the standard logistic function for over a small range of real numbers, such as a range contained in [−6, +6], as it quickly converges very close to its saturation values of 0 and 1.
If the considered function is the density of a normal distribution of the form = [()] where σ is the standard deviation and x 0 is the expected value, then the relationship between FWHM and the standard deviation is [1] = .
It provides a rich Excel-like user interface and its built-in vector programming language FPScript has a syntax similar to MATLAB. FreeMat, an open-source MATLAB-like environment with a GPL license. GNU Octave is a high-level language, primarily intended for numerical computations. It provides a convenient command-line interface for solving ...
Also, the characteristic function of the sample mean X of n independent observations has characteristic function φ X (t) = (e −|t|/n) n = e −|t|, using the result from the previous section. This is the characteristic function of the standard Cauchy distribution: thus, the sample mean has the same distribution as the population itself.