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Methane clathrate (CH 4 ·5.75H 2 O) or (4CH 4 ·23H 2 O), also called methane hydrate, hydromethane, methane ice, fire ice, natural gas hydrate, or gas hydrate, is a solid clathrate compound (more specifically, a clathrate hydrate) in which a large amount of methane is trapped within a crystal structure of water, forming a solid similar to ice.
In organic chemistry, a hydrate is a compound formed by the hydration, i.e. "Addition of water or of the elements of water (i.e. H and OH) to a molecular entity". [5] For example: ethanol , CH 3 −CH 2 −OH , is the product of the hydration reaction of ethene , CH 2 =CH 2 , formed by the addition of H to one C and OH to the other C, and so ...
Methane clathrate block embedded in the sediment of hydrate ridge, off Oregon, USA. Clathrate hydrates, or gas hydrates, clathrates, or hydrates, are crystalline water-based solids physically resembling ice, in which small non-polar molecules (typically gases) or polar molecules with large hydrophobic moieties are trapped inside "cages" of hydrogen bonded, frozen water molecules.
The existence and depth of a hydrate deposit is often indicated by the presence of a bottom-simulating reflector (BSR). A BSR is a seismic reflection indicating the lower limit of hydrate stability in sediments due to the different densities of hydrate saturated sediments, normal sediments and those containing free gas. [2]
The trimer 1,3,5-trioxane, (CH 2 O) 3, is a typical oligomer. Many cyclic oligomers of other sizes have been isolated. Similarly, formaldehyde hydrates to give the geminal diol methanediol, which condenses further to form hydroxy-terminated oligomers HO(CH 2 O) n H. The polymer is called paraformaldehyde. The higher concentration of ...
[3] The term refers to many molecular hosts, including calixarenes and cyclodextrins and even some inorganic polymers such as zeolites. Clathrate cavities. For example, 5 12 (dodecahedral) and 5 12 6 2 (tetrakaidecahedral) make up a Type I (sI) structure. [4] Clathrates can be divided into two categories: clathrate hydrates and inorganic ...
The free gas zone is a zone of freed methane in a hydrate formation, beneath the hydrate stability zone. It can influence the rate of methane output at a ridge or ridge region. A large free gas zone makes more methane available to be released into the open ocean, and, thus, can likely be more influential on climate change than a smaller one. [11]
Because the methane hydrates are unstable, except at cool temperatures and high (deep) pressures, scientists have observed smaller outgassing events due to tectonic events. Studies suggest the huge release of natural gas [ 10 ] could be a major climatological trigger, methane itself being a greenhouse gas many times more powerful than carbon ...