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The exponent, , with which the expansion of the gas can be calculated by the application of heat is called the isentropic – or adiabatic coefficient. Its value is determined by the Rüchardt experiment. An adiabatic and reversible running state change is isentropic (entropy S remains the same as temperature T changes). The technique is ...
The adiabatic (no heat exchanged) expansion of a gas may be carried out in a number of ways. The change in temperature experienced by the gas during expansion depends not only on the initial and final pressure, but also on the manner in which the expansion is carried out.
The adiabatic compression of a gas causes a rise in temperature of the gas. Adiabatic expansion against pressure, or a spring, causes a drop in temperature. In contrast, free expansion is an isothermal process for an ideal gas.
The Joule expansion (a subset of free expansion) is an irreversible process in thermodynamics in which a volume of gas is kept in one side of a thermally isolated container (via a small partition), with the other side of the container being evacuated. The partition between the two parts of the container is then opened, and the gas fills the ...
We assume the expansion occurs without exchange of heat (adiabatic expansion). Doing this work, air inside the cylinder will cool to below the target temperature. To return to the target temperature (still with a free piston), the air must be heated, but is no longer under constant volume, since the piston is free to move as the gas is reheated.
Under other conditions, free-energy change is not equal to work; for instance, for a reversible adiabatic expansion of an ideal gas, =. Importantly, for a heat engine, including the Carnot cycle , the free-energy change after a full cycle is zero, Δ cyc A = 0 {\displaystyle \Delta _{\text{cyc}}A=0} , while the engine produces nonzero work.
The particles in real materials interact with each other. Then, the relation between the pressure, density and temperature is known as the equation of state denoted by some function . The Van der Waals equation is an example of an equation of state for a realistic gas. = (,).
where V 100 is the volume occupied by a given sample of gas at 100 °C; V 0 is the volume occupied by the same sample of gas at 0 °C; and k is a constant which is the same for all gases at constant pressure. This equation does not contain the temperature and so is not what became known as Charles's Law.