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Boron monoxide (BO) is a binary compound of boron and oxygen. It has a molar mass of 26.81 g/mol. It has a molar mass of 26.81 g/mol. The material was first reported in 1940, [ 1 ] with a modified synthetic procedure published in 1955, [ 2 ] however, the material's structure had remained unknown for nearly a century.
Boron monofluoride monoxide or oxoboryl fluoride [2] or fluoroxoborane is an unstable inorganic molecular substance with formula FBO. It is also called boron fluoride oxide, fluoro(oxo)borane or fluoro-oxoborane. The molecule is stable at high temperatures, but below 1000 °C condenses to a trimer (BOF) 3 called trifluoroboroxin.
Boron oxide may refer to one of several oxides of boron: Boron trioxide (B 2 O 3, diboron trioxide), the most common form; Boron monoxide (BO) Boron suboxide (B 6 O)
Atomic structure and electron micrographs of ideal (top) and twinned (bottom) B 6 O. Green spheres are boron, red spheres are oxygen. [8]B 6 O has a strong covalent nature and is easy to compose at temperatures greater than 1,973 K. [7] Boron suboxide has also been reported to exhibit a wide range of superior properties such as high hardness with low density, high mechanical strength ...
This unusual structure, which was deduced only in the 1940's, was an early indication of the many surprises provided by boron chemistry. [49] Structure of diborane. Pyrolysis of diborane gives boron hydride clusters, such as pentaborane(9) B 5 H 9 and decaborane B 10 H 14.
The reaction of boron trichloride with alcohols was reported in 1931, and was used to prepare dimethoxyboron chloride, B(OCH 3) 2 Cl. [3] Egon Wiberg and Wilhelm Ruschmann used it to prepare tetrahydroxydiboron by first introducing the boron–boron bond by reduction with sodium and then hydrolysing the resulting tetramethoxydiboron, B 2 (OCH 3) 4, to produce what they termed sub-boric acid. [4]
Compressing boron above 160 GPa produces a boron phase with an as yet unknown structure. Contrary to other phases, which are semiconductors , this phase is a metal and becomes a superconductor with a critical temperature increasing from 6 K at 160 GPa to 11 K at 250 GPa. [ 48 ]
Sodium metaborate is a chemical compound of sodium, boron, and oxygen with formula NaBO 2. [3] However, the metaborate ion is trimeric in the anhydrous solid, therefore a more correct formula is Na 3 B 3 O 6 or (Na +) 3 [B 3 O 6] 3−. The formula can be written also as Na 2 O·B 2 O 3 to highlight the relation to the main oxides of sodium and ...