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Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
Magnesium hydroxide forms in the presence of water (MgO + H 2 O → Mg(OH) 2), but it can be reversed by heating it to remove moisture. Magnesium oxide was historically known as magnesia alba (literally, the white mineral from Magnesia), to differentiate it from magnesia nigra, a black mineral containing what is now known as manganese.
When finely powdered, magnesium reacts with water to produce hydrogen gas: Mg(s) + 2 H 2 O(g) → Mg(OH) 2 (aq) + H 2 (g) + 1203.6 kJ/mol. However, this reaction is much less dramatic than the reactions of the alkali metals with water, because the magnesium hydroxide builds up on the surface of the magnesium metal and inhibits further reaction ...
Magnesium nitride reacts with water to produce magnesium hydroxide and ammonia gas, as do many metal nitrides.. Mg 3 N 2 (s) + 6 H 2 O(l) → 3 Mg(OH) 2 (aq) + 2 NH 3 (g). In fact, when magnesium is burned in air, some magnesium nitride is formed in addition to the principal product, magnesium oxide.
Magnesium perchlorate is a white powder that is easily soluble in water, which can be obtained by the reaction of magnesium oxide and perchloric acid. The hexahydrate crystallizes from the solution, and then it is dried with phosphorus pentoxide in a vacuum at 200~250 °C to obtain the anhydrous form.
Magnesium hydroxide is an inorganic compound with the chemical formula Mg(OH) 2. It occurs in nature as the mineral brucite. It is a white solid with low solubility in water (K sp = 5.61 × 10 −12). [5] Magnesium hydroxide is a common component of antacids, such as milk of magnesia.
Magnesium sulfate is used to prepare specific cements by the reaction between magnesium oxide and magnesium sulfate solution, which are of good binding ability and more resistance than Portland cement. This cement is mainly utilized in the production of lightweight insulation panels, although its poor water resistance limits its usage.
The most reactive metals, such as sodium, will react with cold water to produce hydrogen and the metal hydroxide: 2 Na (s) + 2 H 2 O (l) →2 NaOH (aq) + H 2 (g) Metals in the middle of the reactivity series, such as iron , will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt ...