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A Maxwell material is the most simple model viscoelastic material showing properties of a typical liquid. It shows viscous flow on the long timescale, but additional elastic resistance to fast deformations. [1] It is named for James Clerk Maxwell who proposed the model in 1867. [2] [3] It is also known as a Maxwell fluid
The generalized Maxwell model, also known as the Wiechert model, is the most general form of the linear model for viscoelasticity. It takes into account that the relaxation does not occur at a single time, but at a distribution of times. Due to molecular segments of different lengths with shorter ones contributing less than longer ones, there ...
Experimentally, stress relaxation is determined by step strain experiments, i.e. by applying a sudden one-time strain and measuring the build-up and subsequent relaxation of stress in the material (see figure), in either extensional or shear rheology. a) Applied step strain and b) induced stress as functions of time for a viscoelastic material.
The shape of the time-dependent strain curve is true to the type of equation that characterizes the behavior of the model over time, depending upon how the model is loaded. Although this model can be used to accurately predict the general shape of the strain curve, as well as behavior for long time and instantaneous loads, the model lacks the ...
The term "relaxation time" has been described. It is used in combination with tests presetting the strain (deformation) or strain rate ( shear rate ), e.g., when performing relaxation tests . On the other hand, the term "retardation time" is used for tests when presetting the stress, e.g., when performing creep tests .
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For this case only two components of the shear stress became non-zero: = ˙ and = ˙ where ˙ is the shear rate.. Thus, the upper-convected Maxwell model predicts for the simple shear that shear stress to be proportional to the shear rate and the first difference of normal stresses is proportional to the square of the shear rate, the second difference of normal stresses is always zero.
Time–temperature superposition is a procedure that has become important in the field of polymers to observe the dependence upon temperature on the change of viscosity of a polymeric fluid. Rheology or viscosity can often be a strong indicator of the molecular structure and molecular mobility.