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A fullerene is an allotrope of carbon whose molecules consist of carbon atoms connected by single and double bonds so as to form a closed or partially closed mesh, with fused rings of five to six atoms.
In other words, although the carbon atoms in fullerene are all conjugated the superstructure is not a super aromatic compound. The X-ray diffraction bond length values are 139.1 pm for the [6,6] bond and 145.5 pm for the [5,6] bond. C 60 fullerene has 60 π electrons but a closed shell configuration requires 72 electrons.
C 70 fullerene is the fullerene molecule consisting of 70 carbon atoms. It is a cage-like fused-ring structure which resembles a rugby ball, made of 25 hexagons and 12 pentagons, with a carbon atom at the vertices of each polygon and a bond along each polygon edge.
These endohedral fullerenes are usually synthesized by doping in the metal atoms in an arc reactor or by laser evaporation. These methods gives low yields of endohedral fullerenes, and a better method involves the opening of the cage, packing in the atoms or molecules, and closing the opening using certain organic reactions. This method ...
Metal atoms (M = Ho or Sc) are seen as dark spots inside the fullerene molecules; they are doubly encapsulated in the C 80 molecules and in the nanotubes. [1] Endohedral fullerenes, also called endofullerenes, are fullerenes that have additional atoms, ions, or clusters enclosed within their inner spheres.
Prismane C 8 is a theoretically predicted metastable carbon allotrope comprising an atomic cluster of eight carbon atoms, with the shape of an elongated triangular bipyramid—a six-atom triangular prism with two more atoms above and below its bases. [45] Protomene: A hexagonal crystal structure with a fully relaxed primitive cell involving 48 ...
Polyfullerene is a basic polymer of the C 60 monomer group, in which fullerene segments are connected via covalent bonds into a polymeric chain without side or bridging groups. They are called intrinsic polymeric fullerenes, or more often all C 60 polymers. Fullerene can be part of a polymer chain in many different ways.
An allotrope of carbon, fullerene—and a particular molecule of that allotrope C 60 (buckminsterfullerene or buckyball) has been named after him. The Buckminsterfullerene molecule, which consists of 60 carbon atoms, very closely resembles a spherical version of Fuller's geodesic dome.