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Example of Frost diagram for the manganese species. A Frost diagram or Frost–Ebsworth diagram is a type of graph used by inorganic chemists in electrochemistry to illustrate the relative stability of a number of different oxidation states of a particular substance.
Frost diagram for manganese In electrochemistry , the tendency of two redox species to disproportionate, or comproportionate, can be determined by examining their Frost diagram . It is a graphical plot of nE ° = −Δ G °/ F as a function of the oxidation number for the different redox species of a given element.
This article is confused and confusing. There are a number of commonly used diagrams, the Latimer diagram, the Frost (sometimes called Frost - Ebsworth) diagram and the pourbaix diagram (also known as Eh-pH diagrams). They are all closely related. A good summary is here . The article seems to describe both the Frost and pourbaix as being the ...
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Latimer diagrams can be used in the construction of Frost diagrams, as a concise summary of the standard electrode potentials relative to the element. Since Δ r G o = -n F E o , the electrode potential is a representation of the Gibbs energy change for the given reduction.
A circle mnemonic [3] was advanced which provides the MO energies of the system; this was the counterpart of the Frost–Musulin mnemonic [6] for ordinary Hückel systems. It was concluded that 4 n electrons is the preferred number for Möbius moieties in contrast to the common 4 n + 2 electrons for Hückel systems.
A three-component compatibility diagram will depict the stable phase of each pure component as the point at each corner of a ternary diagram. Additional points in the diagram represent other pure phases, and lines connecting pairs of these points represent compositions at which the two phases are the only phases present.
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