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In heterogeneous electron transfer, an electron moves between a chemical species present in solution and the surface of a solid such as a semi-conducting material or an electrode. Theories addressing heterogeneous electron transfer have applications in electrochemistry and the design of solar cells.
The work function W for a given surface is defined by the difference [1] =, where −e is the charge of an electron, ϕ is the electrostatic potential in the vacuum nearby the surface, and E F is the Fermi level (electrochemical potential of electrons) inside the material.
An electron transport chain (ETC [1]) is a series of protein complexes and other molecules which transfer electrons from electron donors to electron acceptors via redox reactions (both reduction and oxidation occurring simultaneously) and couples this electron transfer with the transfer of protons (H + ions) across a membrane.
Then the electron mobility μ is defined as =. Electron mobility is almost always specified in units of cm 2 /(V⋅s). This is different from the SI unit of mobility, m 2 /(V⋅s). They are related by 1 m 2 /(V⋅s) = 10 4 cm 2 /(V⋅s). Conductivity is proportional to the product of mobility and carrier concentration. For example, the same ...
Crystalline solids and molecular solids are two opposite extreme cases of materials that exhibit substantially different transport mechanisms. While in atomic solids transport is intra-molecular, also known as band transport, in molecular solids the transport is inter-molecular, also known as hopping transport.
This is because there is an energy to be paid to extract the electron from the medium (work function). Ballistic conduction is typically observed in quasi-1D structures, such as carbon nanotubes or silicon nanowires , because of extreme size quantization effects in these materials.
Elementary steps like proton coupled electron transfer and the movement of electrons between an electrode and substrate are special to electrochemical processes. . Electrochemical mechanisms are important to all redox chemistry including corrosion, redox active photochemistry including photosynthesis, other biological systems often involving electron transport chains and other forms of ...
In theoretical chemistry, Marcus theory is a theory originally developed by Rudolph A. Marcus, starting in 1956, to explain the rates of electron transfer reactions – the rate at which an electron can move or jump from one chemical species (called the electron donor) to another (called the electron acceptor). [1]