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They have the lowest melting points among all transition metals. [8] Zinc is bluish-white and lustrous, [9] though most common commercial grades of the metal have a dull finish. [10] Zinc is also referred to in nonscientific contexts as spelter. [11] Cadmium is soft, malleable, ductile, and with a bluish-white color. Mercury is a liquid, heavy ...
Consequently some of the equivalent salts have the same crystal structure, [57] and in other circumstances where ionic radius is a determining factor, the chemistry of zinc has much in common with that of magnesium. [51] Compared to the transition metals, zinc tends to form bonds with a greater degree of covalency.
The oxygen on an aldehyde or ketone coordinates to the zinc to form the six-member chair like transition state 3. A rearrangement occurs in which zinc switches to the aldehyde or ketone oxygen and a carbon-carbon bond is formed 4. Acid workup 5,6 removes zinc to yield zinc(II) salts and a β-hydroxy-ester 7. [5]
Zinc compounds are chemical compounds containing the element zinc which is a member of the group 12 of the periodic table. The oxidation state of zinc in most compounds is the group oxidation state of +2. Zinc may be classified as a post-transition main group element with zinc(II). Zinc compounds are noteworthy for their nondescript appearance ...
Organozinc chemistry. Organozinc chemistry is the study of the physical properties, synthesis, and reactions of organozinc compounds, which are organometallic compounds that contain carbon (C) to zinc (Zn) chemical bonds.
Naturally occurring zinc (30 Zn) is composed of the 5 stable isotopes 64 Zn, 66 Zn, 67 Zn, 68 Zn, and 70 Zn with 64 Zn being the most abundant (48.6% natural abundance).Twenty-eight radioisotopes have been characterised with the most stable being 65 Zn with a half-life of 244.26 days, and then 72 Zn with a half-life of 46.5 hours.
Zinc smelting has historically been more difficult than the smelting of other metals, e.g. iron, because in contrast, zinc has a low boiling point. At temperatures typically used for smelting metals, zinc is a gas that will escape from a furnace with the flue gas and be lost, unless specific measures are taken to prevent it.
In nuclear science, nuclei of heavy metals such as chromium, iron, or zinc are sometimes fired at other heavy metal targets to produce superheavy elements; [249] heavy metals are also employed as spallation targets for the production of neutrons [250] or isotopes of non-primordial elements such as astatine (using lead, bismuth, thorium, or ...