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The process, which is catalyzed by platinum supported by aluminium oxide, is exemplified in the conversion methylcyclohexane (a naphthene) into toluene (an aromatic). [2] Dehydrocyclization converts paraffins (acyclic hydrocarbons) into aromatics. [3] A related aromatization process includes dehydroisomerization of methylcyclopentane to benzene:
Cyclopentadiene is a highly reactive diene in the Diels–Alder reaction because minimal distortion of the diene is required to achieve the envelope geometry of the transition state compared to other dienes. [11] Famously, cyclopentadiene dimerizes. The conversion occurs in hours at room temperature, but the monomer can be stored for days at ...
Incineration, the combustion of organic material such as waste with energy recovery, is the most common WtE implementation. All new WtE plants in OECD countries incinerating waste (residual MSW, commercial, industrial or RDF) must meet strict emission standards, including those on nitrogen oxides (NO x), sulphur dioxide (SO 2), heavy metals and dioxins.
Materials may be depolymerized in this way during waste management, with the volatile components produced being burnt as a form of synthetic fuel in a waste-to-energy process. For other polymers, thermal depolymerization is an ordered process giving a single product, or limited range of products; these transformations are usually more valuable ...
BRI Energy, LLC [1] is a company whose pilot plant in Fayetteville, Arkansas is currently using synthesis gas fermentation to convert a variety of waste into ethanol. After gasification, anaerobic bacteria (Clostridium ljungdahlii) are used to convert the syngas (CO, CO 2, and H 2) into ethanol. The heat generated by gasification is also used ...
For instance, it is argued that the resonance energy measured experimentally via heats of hydrogenation is diminished by the distortions in bond lengths that must take place going from the single and double bonds of "non-aromatic 1,3,5-cyclohexatriene" to the delocalized bonds of benzene. Taking this distortion energy into account, the value of ...
A waste converter is a machine used for the treatment and recycling of solid and liquid refuse material. A converter is a self-contained system capable of performing the following functions: pasteurization of organic waste; sterilization of pathogenic or biohazard waste; grinding and pulverization of refuse into unrecognizable output; trash compaction; dehydration.
Like the Diels–Alder reaction, the rDA preserves configuration in the diene and dienophile. Much less is known about the relative rates of reversion of endo and exo adducts, and studies have pointed to no correlation between relative configuration in the cyclohexene starting material and reversion rate.