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at 20−25 °C 2.5 g/100 ml 2.4 g/100 ml 1.9 g/100 ml ... The name "cresol" is an adduct of phenol and their traditional source, creosote. Structure and production
Phenol reacts with formaldehyde at the ortho and para sites (sites 2, 4 and 6) allowing up to 3 units of formaldehyde to attach to the ring. The initial reaction in all cases involves the formation of a hydroxymethyl phenol: HOC 6 H 5 + CH 2 O → HOC 6 H 4 CH 2 OH
Para tertiary butylphenol formaldehyde resin, also known as p-tert-butylphenol-formaldehyde resin (PTBP-FR), is a thermoplastic phenol-formaldehyde resin found in commercial adhesives, particularly glues used to bond leather and rubber. It has broad usage in a large variety of industries and can be found in many household textile products and ...
Phenol-formaldehyde resins (PF) were the first commercially relevant impregnation resins, made by reacting phenol and formaldehyde, creating a polymer network inside of the wood upon curing. [7] Phenol can react with formaldehyde at the ortho and para positions, generating mono, di, and trimethylolphenol as the reaction products. [ 6 ]
This makes the hydroxymethyl group an alcohol. It has the identical chemical formula with the methoxy group (−O−CH 3) that differs only in the attachment site and orientation to the rest of the molecule. However, their chemical properties are different. [1] [2] Hydroxymethyl is the side chain of encoded amino acid serine. [3]
These are made by the reaction of phenols, formaldehyde and primary amines which at elevated temperatures (400 °F (200 °C)) undergo ring–opening polymerisation forming polybenzoxazine thermoset networks; when hybridised with epoxy and phenolic resins the resulting ternary systems have glass transition temperatures in excess of 490 °F (250 °C).
A common method for hydroxymethylation involves the reaction of formaldehyde with active C-H and N-H bonds: R 3 C-H + CH 2 O → R 3 C-CH 2 OH R 2 N-H + CH 2 O → R 2 N-CH 2 OH. A typical active C-H bond is provided by a terminal acetylene [1] or the alpha protons of an aldehyde. [2]
Hexion offers resins for a wide range of applications like Abrasives, Adhesives, Chemical Intermediates, Civil Engineering, Coatings, Composites, Crop Protection, Electrical/Electronics, Engineered Wood, Fertilizers and Pesticides, Fibers and Textiles, Foams, Friction Materials, Furniture, Molding Compounds, Oilfield, Oriented Strand Board ...