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Cyanuric chloride is employed as a reagent in organic synthesis for the conversion of alcohols into alkyl chlorides, [8] and carboxylic acids into acyl chlorides: [9]. It is also used as a dehydrating agent, e.g. in the conversion of amides to nitriles, [10] and for the activation of carboxylic acids for reduction to alcohols.
Simazine may be prepared from cyanuric chloride and a concentrated solution of ethyl amine (at least 50 percent by number) in water. [1] The reaction is highly exothermic and is therefore best carried out below 10 °C.
Beckmann rearrangement can be rendered catalytic using cyanuric chloride and zinc chloride as a co-catalyst. For example, cyclododecanone can be converted to the corresponding lactam, the monomer used in the production of Nylon 12. [8] [9] Beckmann reaction. The reaction mechanism for this reaction is based on a catalytic cycle with cyanuric ...
When using oxalyl chloride as the dehydration agent, the reaction must be kept colder than −60 °C to avoid side reactions. With cyanuric chloride [11] or trifluoroacetic anhydride [12] instead of oxalyl chloride, the reaction can be warmed to −30 °C without side reactions.
With amines, one or more chloride is displaced. The remaining chlorides are reactive, and this theme is the basis of the large field of reactive dyes. Cyanuric chloride assists in the amidation of carboxylic acids. [3] The 1,2,4-triazines can react with electron-rich dienophiles in an inverse electron demand Diels-Alder reaction. This forms a ...
The Schotten–Baumann reaction is a method to synthesize amides from amines and acid chlorides: An example of a Schotten-Baumann reaction. Benzylamine reacts with acetyl chloride under Schotten-Baumann conditions to form N-benzylacetamide. Schotten–Baumann reaction also refers to the conversion of acid chloride to esters.
Inorganic chloramines are produced by the reaction of ammonia and hypochlorous acid or chlorine. An urban legend claims that mixing household bleach (aqueous sodium hypochlorite) with ammonia-based cleaners releases chlorine gas or mustard gas; in reality, the gas produced by the reaction is a mixture of inorganic chloramines.
The Leuckart reaction is the chemical reaction that converts aldehydes or ketones to amines. The reaction is an example of reductive amination. [1] The reaction, named after Rudolf Leuckart, uses either ammonium formate or formamide as the nitrogen donor and reducing agent. It requires high temperatures, usually between 120 and 130 °C; for the ...