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Many crystal structures are based on a close-packing of a single kind of atom, or a close-packing of large ions with smaller ions filling the spaces between them. The cubic and hexagonal arrangements are very close to one another in energy, and it may be difficult to predict which form will be preferred from first principles.
The nickel arsenide structure consists of two interpenetrating sublattices: a primitive hexagonal nickel sublattice and a hexagonal close-packed arsenic sublattice. Each nickel atom is octahedrally coordinated to six arsenic atoms, while each arsenic atom is trigonal prismatically coordinated to six nickel atoms. [15]
HCP structure. For the hexagonal close-packed structure the derivation is similar. Here the unit cell (equivalent to 3 primitive unit cells) is a hexagonal prism containing six atoms (if the particles in the crystal are atoms).
This category lists every chemical element that exists in a hexagonal close packed structure at STP. Pages in category "Chemical elements with hexagonal close-packed structure" The following 27 pages are in this category, out of 27 total.
In closest packing, every atom has 12 equidistant nearest neighbours, and therefore a coordination number of 12. If the close packed structures are considered as being built of layers of spheres, then the difference between hexagonal close packing and face-centred cubic is how each layer is positioned relative to others.
This arrangement of atoms in a crystal structure is known as hexagonal close packing (hcp). If, however, all three planes are staggered relative to each other and it is not until the fourth layer is positioned directly over plane A that the sequence is repeated, then the following sequence arises:
Slip in hexagonal close packed (hcp) metals is much more limited than in bcc and fcc crystal structures. Usually, hcp crystal structures allow slip on the densely packed basal {0001} planes along the <11 2 0> directions. The activation of other slip planes depends on various parameters, e.g. the c/a ratio.
Hexaferrum and epsilon iron (ε-Fe) are synonyms for the hexagonal close-packed (HCP) phase of iron that is stable only at extremely high pressure.. A 1964 study at the University of Rochester mixed 99.8% pure α-iron powder with sodium chloride, and pressed a 0.5-mm diameter pellet between the flat faces of two diamond anvils.