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An intermolecular force (IMF; also secondary force) is the force that mediates interaction between molecules, including the electromagnetic forces of attraction or repulsion which act between atoms and other types of neighbouring particles, e.g. atoms or ions. Intermolecular forces are weak relative to intramolecular forces – the forces which ...
t. e. In chemistry and physics, cohesion (from Latin cohaesiō 'cohesion, unity'), also called cohesive attraction or cohesive force, is the action or property of like molecules sticking together, being mutually attractive. It is an intrinsic property of a substance that is caused by the shape and structure of its molecules, which makes the ...
Definition. Van der Waals forces include attraction and repulsions between atoms, molecules, as well as other intermolecular forces. They differ from covalent and ionic bonding in that they are caused by correlations in the fluctuating polarizations of nearby particles (a consequence of quantum dynamics [6]). The force results from a transient ...
An ideal gas is a theoretical gas composed of many randomly moving point particles that are not subject to interparticle interactions. [1] The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state, and is amenable to analysis under statistical mechanics. The requirement of zero interaction can often be ...
If appropriate assumptions are made about the mathematical form of intermolecular forces, theoretical expressions can be developed for each of the coefficients. A is the first virial coefficient, which has a constant value of 1 and makes the statement that when volume is large, all fluids behave like ideal gases.
The black curve corresponds to the Lennard-Jones potential. The Mie potential is an interaction potential describing the interactions between particles on the atomic level. It is mostly used for describing intermolecular interactions, but at times also for modeling intramolecular interaction, i.e. bonds. The Mie potential is named after the ...
The van der Waals equation, named for its originator, the Dutch physicist Johannes Diderik van der Waals, is an equation of state that extends the ideal gas law to include the non-zero size of gas molecules and the interactions between them (both of which depend on the specific substance). As a result the equation is able to model the phase ...
The gray, red, and purple balls represent carbon, oxygen, and nitrogen, respectively. Images of carbon dioxide (b) and caffeine (d) in the solid state at room temperature and atmosphere. The gaseous phase of the dry ice in image (b) is visible because the molecular solid is subliming. A molecular solid is a solid consisting of discrete molecules.