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The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Lead perchlorate trihydrate is produced by the reaction of lead(II) oxide, lead carbonate, or lead nitrate by perchloric acid: . Pb(NO 3) 2 + HClO 4 → Pb(ClO 4) 2 + HNO 3. The excess perchloric acid was removed by first heating the solution to 125 °C, then heating it under moist air at 160 °C to remove the perchloric acid by converting the acid to the dihydrate.
Lead(II) chloride is the main precursor for organometallic derivatives of lead, such as plumbocenes. [11] The usual alkylating agents are employed, including Grignard reagents and organolithium compounds: 2 PbCl 2 + 4 RLi → R 4 Pb + 4 LiCl + Pb 2 PbCl 2 + 4 RMgBr → R 4 Pb + Pb + 4 MgBrCl 3 PbCl 2 + 6 RMgBr → R 3 Pb-PbR 3 + Pb + 6 MgBrCl [12]
It is then converted to the ammonium salt (NH 4) 2 PbCl 6 by adding ammonium chloride (NH 4 Cl). Finally, the solution is treated with concentrated sulfuric acid H 2 SO 4, to separate out lead tetrachloride. This series of reactions is conducted at 0 °C. The following equations illustrate the reaction: PbCl 2 + 2HCl + Cl 2 → H 2 PbCl 6
Lead(II) azide is prepared by the reaction of sodium azide and lead(II) nitrate in aqueous solution. [6] [5] Lead(II) acetate can also be used.[7] [8]Thickeners such as dextrin or polyvinyl alcohol are often added to the solution to stabilize the precipitated product.
3 Cl 2 + 6 LiOH → 5 LiCl + LiClO 3 + 3 H 2 O. Lithium chlorate has one of the highest solubilities in water for a chemical compound. It is also a six-electron oxidant. Its electrochemical reduction is facilitated by acid, electrocatalysts and redox mediators. These properties make lithium chlorate a useful oxidant for high energy density flow ...
2 is commonly synthesized via a precipitation reaction between potassium iodide KI and lead(II) nitrate Pb (NO 3) 2 in water solution: Pb(NO 3) 2 + 2 KI → PbI 2 + 2 KNO 3. While the potassium nitrate KNO 3 is soluble, the lead iodide PbI 2 is nearly insoluble at room temperature, and thus precipitates out. [17]
Sodium chlorate is an inorganic compound with the chemical formula Na ClO 3.It is a white crystalline powder that is readily soluble in water. It is hygroscopic.It decomposes above 300 °C to release oxygen [4] and leaves sodium chloride.