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Temperature-dependency of the heats of vaporization for water, methanol, benzene, and acetone. In thermodynamics, the enthalpy of vaporization (symbol ∆H vap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy that must be added to a liquid substance to transform a quantity of that substance into a gas.
The terms sensible heat and latent heat refer to energy transferred between a body and its surroundings, defined by the occurrence or non-occurrence of temperature change; they depend on the properties of the body. Sensible heat is sensed or felt in a process as a change in the body's temperature.
Equivalent potential temperature, commonly referred to as theta-e (), is a quantity that is conserved during changes to an air parcel's pressure (that is, during vertical motions in the atmosphere), even if water vapor condenses during that pressure change.
Liquid water that becomes water vapor takes a parcel of heat with it, in a process called evaporative cooling. [3] The amount of water vapor in the air determines how frequently molecules will return to the surface. When a net evaporation occurs, the body of water will undergo a net cooling directly related to the loss of water.
Evaporation is an essential part of the water cycle. The sun (solar energy) drives evaporation of water from oceans, lakes, moisture in the soil, and other sources of water. In hydrology, evaporation and transpiration (which involves evaporation within plant stomata) are collectively termed evapotranspiration. Evaporation of water occurs when ...
: latent heat of evaporation (2400 kJ/kg at 25°C to 2600 kJ/kg at −40°C) c p d {\displaystyle c_{pd}} : specific heat at constant pressure for air (≈ 1004 J/(kg·K)) Tables exist for exact values of the last two coefficients.
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
The energy needed to evaporate the water is taken from the air in the form of sensible heat and converted into latent heat, while the air remains at a constant enthalpy. Latent heat describes the amount of heat that is needed to evaporate the liquid; this heat comes from the liquid itself and the surrounding gas and surfaces.