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Temperature-dependency of the heats of vaporization for water, methanol, benzene, and acetone. In thermodynamics, the enthalpy of vaporization (symbol ∆H vap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy that must be added to a liquid substance to transform a quantity of that substance into a gas.
λ v = latent heat of vaporization (J kg −1) γ = psychrometric constant (Pa K −1) which (if the SI units in parentheses are used) will give the evaporation E mass in units of kg/(m 2 ·s), kilograms of water evaporated every second for each square meter of area. Remove λ to obviate that this is fundamentally an energy balance.
λ v = Latent heat of vaporization. The energy required per unit mass of water vaporized. (J g −1) L v = Volumetric latent heat of vaporization. The energy required per unit volume of water vaporized. (L v = 2453 MJ m −3) E = Mass water evapotranspiration rate (g s −1 m −2) ET = Water volume evapotranspired (mm s −1)
In meteorology, latent heat flux is the flux of energy from the Earth's surface to the atmosphere that is associated with evaporation or transpiration of water at the surface and subsequent condensation of water vapor in the troposphere. It is an important component of Earth's surface energy budget.
L is the latent heat of vaporization at the temperature T, T C is the critical temperature, L 0 is the parameter that is equal to the heat of vaporization at zero temperature (T → 0), tanh is the hyperbolic tangent function. This equation was obtained in 1955 by Yu. I. Shimansky, at first empirically, and later derived theoretically.
where is the heat or enthalpy of vaporization. Since this is a thermodynamic equation, the symbol refers to the absolute thermodynamic temperature, measured in kelvins (K). The entropy of vaporization is then equal to the heat of vaporization divided by the boiling point: [2] [3]
The rule, however, has some exceptions. For example, the entropies of vaporization of water, ethanol, formic acid and hydrogen fluoride are far from the predicted values. The entropy of vaporization of XeF 6 at its boiling point has the extraordinarily high value of 136.9 J/(K·mol). [4]
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds