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The mean and the standard deviation of a set of data are descriptive statistics usually reported together. In a certain sense, the standard deviation is a "natural" measure of statistical dispersion if the center of the data is measured about the mean. This is because the standard deviation from the mean is smaller than from any other point.
In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. [1] In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures ...
Common examples of measures of statistical dispersion are the variance, standard deviation, and interquartile range. For instance, when the variance of data in a set is large, the data is widely scattered. On the other hand, when the variance is small, the data in the set is clustered.
A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
σ g: Geometric standard deviation. This value is determined mathematically by the equation: σ g = D 84.13 /D 50 = D 50 /D 15.87. The value of σ g determines the slope of the least-squares regression curve. α: Relative standard deviation or degree of polydispersity. This value is also determined mathematically.
2 consecutive measurements exceed 2 standard deviations of the reference range, and on the same side of the mean. Inaccuracy and/or imprecision R 4s: Two measurements in the same run have a 4 standard deviation difference (such as one exceeding 2 standard deviations above the mean, and another exceeding 2 standard deviations below the mean).
In analytical chemistry, a standard solution (titrant or titrator) is a solution containing an accurately known concentration.Standard solutions are generally prepared by dissolving a solute of known mass into a solvent to a precise volume, or by diluting a solution of known concentration with more solvent. [1]
When determining the stability constants of metal-ligand complexes, it is common practice to fix ligand protonation constants at values that have been determined using data obtained from metal-free solutions. Hydrolysis constants of metal ions are usually fixed at values which were obtained using ligand-free solutions.