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The kinetic theory of gases deals not only with gases in thermodynamic equilibrium, but also very importantly with gases not in thermodynamic equilibrium. This means using Kinetic Theory to consider what are known as "transport properties", such as viscosity, thermal conductivity, mass diffusivity and thermal diffusion.
The positive part models the repulsive forces as the electron clouds of the two molecules overlap. The radius for zero interaction potential is therefore appropriate for estimating (or defining) the collision cross section in kinetic gas theory, and the r-parameter (conf. ,) is therefore called kinetic radius.
Lectures on gas theory. (1896, 1898) Translated by Stephen G. Brush (1964) Berkeley: University of California Press; (1995) New York: Dover ISBN 0-486-68455-5; Gibbs, Josiah Willard (1902). Elementary Principles in Statistical Mechanics, developed with especial reference to the rational foundation of thermodynamics. New York: Charles Scribner's ...
The laws describing the behaviour of gases under fixed pressure, volume, amount of gas, and absolute temperature conditions are called gas laws.The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.
This article inspired further work based on the twin ideas that substances are composed of indivisible particles, and that heat is a consequence of the particle motion; movement that evolves in accordance with Newton's laws. The work, known as the kinetic theory of gases, was done principally by Clausius, James Clerk Maxwell, and Ludwig Boltzmann.
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
Kinetic theory may refer to: Kinetic theory of matter: A general account of the properties of matter, including solids liquids and gases, based around the idea that heat or temperature is a manifestation of atoms and molecules in constant agitation. Kinetic theory of gases, an account of gas properties in terms of motion and interaction of ...
In statistical physics, the kinetic theory of gases applies Newton's laws of motion to large numbers (typically on the order of the Avogadro number) of particles. Kinetic theory can explain, for example, the pressure that a gas exerts upon the container holding it as the aggregate of many impacts of atoms, each imparting a tiny amount of momentum.