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The sublimation that occurs at the solid-gas boundary (critical sublimation point) (corresponding to boiling in vaporization) may be called rapid sublimation, and the substance sublimes rapidly. The words "gradual" and "rapid" have acquired special meanings in this context and no longer describe the rate of sublimation.
In physics, chemistry, and other related fields like biology, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter : solid , liquid , and gas , and in rare cases, plasma .
Sublimation or sublimate may refer to: Sublimation, by Canvas Solaris, 2004; Sublimation (phase transition), directly from the solid to the gas phase; Sublimation (psychology), a mature type of defense mechanism; Sublimate of mercury, or Mercury(II) chloride; Volcanic sublimate, a product of deposition from vapors around volcanic vents
In thermodynamics, the enthalpy of sublimation, or heat of sublimation, is the heat required to sublimate (change from solid to gas) one mole of a substance at a given combination of temperature and pressure, usually standard temperature and pressure (STP). It is equal to the cohesive energy of the solid.
Outgassing is a challenge to creating and maintaining clean high-vacuum environments.NASA and ESA maintain lists of materials with low-outgassing properties suitable for use in spacecraft, as outgassing products can condense onto optical elements, thermal radiators, or solar cells and obscure them.
Examples can include Latent internal energy of vaporization (liquid to vapor), Latent internal energy of crystallization (liquid to solid) Latent internal energy of sublimation (solid to vapor). These values are usually expressed in units of energy per mole or per mass such as J /mol or BTU /lb.
A sublimatory [1] [2] or sublimation apparatus is equipment, commonly laboratory glassware, for purification of compounds by selective sublimation. In principle, the operation resembles purification by distillation , except that the products do not pass through a liquid phase .
One example of deposition is the process by which, in sub-freezing air, water vapour changes directly to ice without first becoming a liquid. This is how frost and hoar frost form on the ground or other surfaces. Another example is when frost forms on a leaf. For deposition to occur, thermal energy must be removed from a gas.