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Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. [ 1 ] [ 2 ] This was first introduced by Burnaby Munson and Frank H. Field in 1966. [ 3 ] This technique is a branch of gaseous ion-molecule chemistry. [ 2 ]
A certain amount of energy, which may be large enough, is required to remove an electron from an atom or a molecule in its ground state. [12] [13] In chemi-ionization processes, the energy consumed by the ionization must be stored in atoms or molecules in a form of potencial energy or can be obtained from an accompanying exothermic chemical change (for example, from a formation of a new ...
Atmospheric pressure chemical ionization chamber cross section. Atmospheric pressure chemical ionization (APCI) is an ionization method used in mass spectrometry which utilizes gas-phase ion-molecule reactions at atmospheric pressure (10 5 Pa), [1] [2] commonly coupled with high-performance liquid chromatography (HPLC). [3]
Ionization (or ionisation specifically in Britain, Ireland, South Africa, Australia and New Zealand) is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes.
Chemical ionization (CI) is a lower energy process than electron ionization because it involves ion/molecule reactions rather than electron removal. [6] The lower energy yields less fragmentation , and usually a simpler spectrum .
The first molar ionization energy applies to the neutral atoms. The second, third, etc., molar ionization energy applies to the further removal of an electron from a singly, doubly, etc., charged ion. For ionization energies measured in the unit eV, see Ionization energies of the elements (data page). All data from rutherfordium onwards is ...
Charge-exchange ionization (also called charge-transfer ionization) is a gas phase reaction between an ion and a neutral species A + + B → A + B + {\displaystyle A^{+}+B\to A+B^{+}} in which the charge of the ion is transferred to the neutral.
Conventional ionization technologies compared to the SICRIT technology. Several reaction pathways have been identified that lead to ionization during this process: [4] The proton transfer via hydronium clusters, similar to spray-based methods (c. ESI). The hydronium cluster mechanism as with chemical methods (cf. APCI).