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The same conversion can be effected with elemental bromine in the presence of UV light or even sunlight. Toluene may also be brominated by treating it with HBr and H 2 O 2 in the presence of light. [31] C 6 H 5 CH 3 + Br 2 → C 6 H 5 CH 2 Br + HBr. Benzoic acid and benzaldehyde are produced commercially by partial oxidation of toluene with oxygen.
The entropy of vaporization of XeF 6 at its boiling point has the extraordinarily high value of 136.9 J/(K·mol). [4] The characteristic of those liquids to which Trouton’s rule cannot be applied is their special interaction between molecules, such as hydrogen bonding. The entropy of vaporization of water and ethanol shows positive deviance ...
Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: 184.3 ... Toluene: 0.82 110.6 [28] Dimethyl Sulfoxide: 189.0
Triple point: 178.15 K (−94.99 °C), ? Pa Critical point: 591.79 K (318.64 °C), 4.109 MPa Std enthalpy change of fusionΔ fus H o: 6.636 kJ/mol Std entropy change of fusionΔ fus S o: 37.25 J/(mol·K) Std enthalpy change of vaporizationΔ vap H o: 38.06 kJ/mol Std entropy change of vaporizationΔ vap S o: 87.30 J/(mol·K) Solid properties ...
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
The Antoine equation is a class of semi-empirical correlations describing the relation between vapor pressure and temperature for pure substances. The Antoine equation is derived from the Clausius–Clapeyron relation. The equation was presented in 1888 by the French engineer Louis Charles Antoine (1825–1897). [1]
This is a collection of temperature conversion formulas and comparisons among eight different temperature scales, several of which have long been obsolete.. Temperatures on scales that either do not share a numeric zero or are nonlinearly related cannot correctly be mathematically equated (related using the symbol =), and thus temperatures on different scales are more correctly described as ...
There are two conventions regarding the standard boiling point of water: The normal boiling point is commonly given as 100 °C (212 °F) (actually 99.97 °C (211.9 °F) following the thermodynamic definition of the Celsius scale based on the kelvin) at a pressure of 1 atm (101.325 kPa).