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Octahedral (red) and tetrahedral (blue) interstitial symmetry polyhedra in a face-centered cubic lattice. The actual interstitial atom would ideally be in the middle of one of the polyhedra. A close packed unit cell, both face-centered cubic and hexagonal close packed, can form two different shaped holes.
Interstitial atoms (blue) occupy some of the spaces within a lattice of larger atoms (red) In materials science, an interstitial defect is a type of point crystallographic defect where an atom of the same or of a different type, occupies an interstitial site in the crystal structure.
The modern definition of the law of symmetry is based on symmetry elements, and is more in the German dynamistic [1] crystallographic tradition of Christian Samuel Weiss, Moritz Ludwig Frankenheim and Johann F. C. Hessel. Weiss and his followers studied the external symmetry of crystals rather than their internal structure.
Model of the carbon split-interstitial in diamond. Isolated interstitial has never been observed in diamond and is considered unstable. Its interaction with a regular carbon lattice atom produces a "split-interstitial", a defect where two carbon atoms share a lattice site and are covalently bonded with the carbon neighbors.
This structure is often confused for a body-centered cubic structure because the arrangement of atoms is the same. However, the caesium chloride structure has a basis composed of two different atomic species. In a body-centered cubic structure, there would be translational symmetry along the [111] direction.
The defining property of a crystal is its inherent symmetry. Performing certain symmetry operations on the crystal lattice leaves it unchanged. All crystals have translational symmetry in three directions, but some have other symmetry elements as well. For example, rotating the crystal 180° about a certain axis may result in an atomic ...
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The (finite) list of all symmetry operations which leave the given point invariant taken together make up another group, which is known as the site symmetry group of that point. [4] By definition, all points with the same site symmetry group, or a conjugate site symmetry group, are assigned the same Wyckoff position.