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The structure according to Pauling's General Chemistry Vapor-liquid equilibrium above an aqueous solution of chlorine dioxide at various temperatures. The molecule ClO 2 has an odd number of valence electrons, and therefore, it is a paramagnetic radical.
[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
Chlorine and oxygen can bond in a number of ways: chlorine monoxide radical, ClO•, chlorine (II) oxide radical; chloroperoxyl radical, ClOO•, chlorine (II) peroxide radical; chlorine dioxide, ClO 2, chlorine (IV) oxide; chlorine trioxide radical, ClO 3 •, chlorine (VI) oxide radical; chlorine tetroxide radical, ClO 4 •, chlorine (VII ...
The chlorite ion adopts a bent molecular geometry, due to the effects of the lone pairs on the chlorine atom, with an O–Cl–O bond angle of 111° and Cl–O bond lengths of 156 pm. [1] Chlorite is the strongest oxidiser of the chlorine oxyanions on the basis of standard half cell potentials.
The structure of dichlorine monoxide is similar to that of water and hypochlorous acid, with the molecule adopting a bent molecular geometry (due to the lone pairs on the oxygen atom) and resulting in C 2V molecular symmetry. The bond angle is slightly larger than normal, likely due to steric repulsion between the bulky chlorine atoms.
The term chloride refers to a compound or molecule that contains either a chlorine anion (Cl −), which is a negatively charged chlorine atom, or a non-charged chlorine atom covalently bonded to the rest of the molecule by a single bond (−Cl). Many inorganic chlorides are salts. Many organic compounds are chlorides.
However, in liquid or solid form, this chlorine oxide ionizes into the dark red ionic compound chloryl perchlorate [ClO 2] + [ClO 4] −, which may be thought of as the mixed anhydride of chloric and perchloric acids. This compound is a notable perchlorating agent. [1] It is produced by reaction between chlorine dioxide and excess ozone: 2 ClO ...
Dichlorine heptoxide is a covalent compound consisting of two ClO 3 portions linked by an oxygen atom. It has an overall bent molecular geometry (C 2 symmetry ), with a Cl−O−Cl angle of 118.6°. The chlorine–oxygen bond lengths are 1.709 Å in the central region and 1.405 Å within each ClO 3 cluster. [ 1 ]