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The autoignition temperature or self-ignition temperature, often called spontaneous ignition temperature or minimum ignition temperature (or shortly ignition temperature) and formerly also known as kindling point, of a substance is the lowest temperature at which it spontaneously ignites in a normal atmosphere without an external source of ignition, such as a flame or spark. [1]
The δ phase is the least dense and most easily machinable. It is formed at temperatures of 310–452 °C at ambient pressure (1 atmosphere), and is thermodynamically unstable at lower temperatures. However, plutonium can be stabilized in the δ phase by alloying it with a small amount of another metal.
Trace amounts of plutonium-238, plutonium-239, plutonium-240, and plutonium-244 can be found in nature. Small traces of plutonium-239, a few parts per trillion , and its decay products are naturally found in some concentrated ores of uranium, [ 54 ] such as the natural nuclear fission reactor in Oklo , Gabon . [ 55 ]
The pits of the first nuclear weapons were solid, with an urchin neutron initiator in their center. The Gadget and Fat Man used pits made of 6.2 kg of solid hot pressed plutonium-gallium alloy (at 400 °C and 200 MPa in steel dies – 750 °F and 29,000 psi) half-spheres of 9.2 cm (3.6 in) diameter, with a 2.5 cm (1 in) internal cavity for the initiator.
As plutonium cools, changes in phase result in distortion and cracking. This distortion is normally overcome by alloying it with 30–35 mMol (0.9–1.0% by weight) gallium, forming a plutonium-gallium alloy, which causes it to take up its delta phase over a wide temperature range. [21]
Plutonium in the delta (δ) phase [8] normally exists in the 310 °C to 452 °C range but is stable at room temperature when alloyed with a small percentage of gallium, aluminium, or cerium, enhancing workability and allowing it to be welded in weapons applications. The δ phase has more typical metallic character and is roughly as strong and ...
To reduce the concentration of Pu-240 in the plutonium produced, weapons program plutonium production reactors (e.g. B Reactor) irradiate the uranium for a far shorter time than is normal for a nuclear power reactor. More precisely, weapons-grade plutonium is obtained from uranium irradiated to a low burnup.
Any fuel-air mixture higher than this would be too concentrated to result in combustion. The values existing between these two limits represent the flammable or explosive range. Within this threshold, give an external ignition source, combustion of the particular fuel would likely happen.