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The complex can be synthesized by the reaction between iron(III) sulfate, barium oxalate and potassium oxalate: [4] Fe 2 (SO 4) 3 + 3 BaC 2 O 4 + 3 K 2 C 2 O 4 → 2 K 3 [Fe(C 2 O 4) 3] + 3 BaSO 4. As can be read in the reference above, iron(III) sulfate, barium oxalate and potassium oxalate are combined in water and digested for several hours ...
Potassium ferrioxalate crystals. Metal oxalate complexes are photoactive, degrading with loss of carbon dioxide. This reaction is the basis of the technique called actinometry. Ferrioxalate undergoes photoreduction. The iron centre is reduced (gains an electron) from the +3 to the +2 oxidation state, while an oxalate ion is oxidised to carbon ...
The alkylphosphonium salt is deprotonated with a strong base such as n-butyllithium: [Ph 3 P + CH 2 R]X − + C 4 H 9 Li → Ph 3 P=CHR + LiX + C 4 H 10. Besides n-butyllithium (n BuLi), other strong bases like sodium and potassium t-butoxide (t BuONa, t BuOK), lithium, sodium and potassium hexamethyldisilazide (LiHMDS, NaHMDS, KHDMS, where HDMS = N(SiMe 3) 2), or sodium hydride (NaH) are also ...
Ferrioxalate or trisoxalatoferrate(III) is a trivalent anion with formula [Fe(C 2 O 4) 3] 3−.It is a transition metal complex consisting of an iron atom in the +3 oxidation state and three bidentate oxalate ions C 2 O 2− 4 anions acting as ligands.
The anhydrous product is a white, odorless, crystalline solid, hygroscopic and soluble in water (2.5 g/100 g at room temperature). The solutions are basic. Below 50 °C the much less soluble "potassium tetraoxalate" K + [C 2 HO 4] − • C 2 H 2 O 4 forms and precipitates out of solution. [5] The monohydrate KHC 2 O 4 ·H 2 O starts losing the ...
Potassium chlorochromate is an inorganic compound with the formula KCrO 3 Cl. [4] It is the potassium salt of chlorochromate, [CrO 3 Cl] −. It is a water-soluble orange compound is used occasionally for oxidation of organic compounds. It is sometimes called Péligot's salt, in recognition of its discoverer Eugène-Melchior Péligot.
It can be prepared by treating a potassium-containing base such as potassium hydroxide or potassium carbonate with acetic acid: CH 3 COOH + KOH → CH 3 COOK + H 2 O. This sort of reaction is known as an acid-base neutralization reaction. At saturation, the sesquihydrate in water solution (CH 3 COOK·1½H 2 O) begins to form semihydrate at 41.3 ...
Potassium picrate was first prepared in impure form in the mid 17th century by Johann Rudolf Glauber by dissolving wood in nitric acid and neutralizing with potassium carbonate. It is commonly made by neutralizing picric acid with potassium carbonate. It has been used in industry since the 1860s. [1]