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The Borate Minerals are minerals which contain a borate anion group. The borate (BO 3) units may be polymerised similar to the SiO 4 unit of the silicate mineral class. This results in B 2 O 5, B 3 O 6, B 2 O 4 anions as well as more complex structures which include hydroxide or halogen anions. [2] The [B(O,OH) 4] − anion exists as well.
Borate fusion and energy dispersive X-ray fluorescence spectrometry with polarized excitation have been used in the analysis of contaminated soils. [14] Disodium octaborate tetrahydrate Na 2 B 8 O 13 ·4H 2 O (commonly abbreviated DOT) is used as a wood preservative or fungicide. Zinc borate is used as a flame retardant.
Painite is a very rare borate mineral. It was first found in Myanmar by British mineralogist and gem dealer Arthur C.D. Pain who misidentified it as ruby, until it was discovered as a new gemstone in the 1950s. When it was confirmed as a new mineral species, the mineral was named after him. [3]
Ulexite is a borate mineral because its formula (NaCaB 5 O 6 (OH) 6 ·5H 2 O) contains boron and oxygen. The isolated borate polyanion [B 5 O 6 (OH) 6] 3− has five boron atoms, therefore placing ulexite in the pentaborate group. Ulexite is a structurally complex mineral, with a basic structure containing chains of sodium, water and hydroxide ...
Boracite is a magnesium borate mineral with formula: Mg 3 B 7 O 13 Cl. It occurs as blue green, colorless, gray, yellow to white crystals in the orthorhombic - pyramidal crystal system. Boracite also shows pseudo-isometric cubical and octahedral forms. These are thought to be the result of transition from an unstable high temperature isometric ...
A common borate is borax, which has been used in soaps as a surfactant. Carbonates: such as trona, formed in inland brine lakes. Some evaporite minerals, such as hanksite, are from multiple groups. Evaporite minerals start to precipitate when their concentration in water reaches such a level that they can no longer exist as solutes.
Borax (Na 2 B 4 O 5 (OH) 4 · 8 H 2 O [2]) is a borate mineral found in evaporite deposits of alkaline lacustrine environments and as a surface efflorescence in arid regions. It is the chief mineral mined from the deposits at Boron, California and nearby locations, and is the chief source of commercial borax.
Unlike silicates, boron minerals never contain boron with coordination number greater than four. A typical motif is exemplified by the tetraborate anions of the common mineral borax, shown at left. The formal negative charge of the tetrahedral borate center is balanced by metal cations in the minerals, such as the sodium (Na +) in borax. [1]