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Phosphorus pentasulfide is the inorganic compound with the formula P 2 S 5 or P 4 S 10 . This yellow solid is the one of two phosphorus sulfides of commercial value. Samples often appear greenish-gray due to impurities. It is soluble in carbon disulfide but reacts with many other solvents such as alcohols, DMSO, and DMF.
Phosphorus sulfides comprise a family of inorganic compounds containing only phosphorus and sulfur.These compounds have the formula P 4 S n with n ≤ 10. Two are of commercial significance, phosphorus pentasulfide (P 4 S 10), which is made on a kiloton scale for the production of other organosulfur compounds, and phosphorus sesquisulfide (P 4 S 3), used in the production of "strike anywhere ...
Diphosphenes, with the formula R 2 P 2, formally contain phosphorus-phosphorus double bonds. These phosphorus(I) species are rare but are stable provided that the organic substituents are large enough to prevent catenation. Bulky substituents also stabilize phosphorus radicals. Many mixed-valence compounds are known, e.g. the cage P 7 (CH 3) 3.
Phosphorus pentabromide – PBr 5; Phosphorus pentafluoride – PF 5; Phosphorus pentasulfide – P 4 S 10; Phosphorus pentoxide – P 2 O 5; Phosphorus sesquisulfide – P 4 S 3; Phosphorus tribromide – PBr 3; Phosphorus trichloride – PCl 3; Phosphorus trifluoride – PF 3; Phosphorus triiodide – PI 3; Phosphotungstic acid – H 3 PW 12 ...
Thiones are usually prepared from ketones using reagents that exchange S and O atoms. A common reagent is phosphorus pentasulfide, [9] although that reagent also tends to induce side-reactions. [10]: 928 Lawesson's reagent is related. Other methods uses a mixture of hydrogen chloride combined with hydrogen sulfide.
White phosphorus is widely used to make organophosphorus compounds through intermediate phosphorus chlorides and two phosphorus sulfides, phosphorus pentasulfide and phosphorus sesquisulfide. [116] Organophosphorus compounds have many applications, including in plasticisers , flame retardants , pesticides , extraction agents, nerve agents and ...
The anion has an ethane-like structure and contains a P−P bond. The formal oxidation state of phosphorus is +4. The oxygen analogue is the hypodiphosphate anion, P 2 O 4− 6. P 3 S 3− 9 contains a six-membered P 3 S 3 ring. The ammonium salt is produced by reaction of P 4 S 10 in liquid ammonia. [13]
Arsenic pentasulfide, As 2 S 5, similar structure to phosphorus pentasulfide (β-P 2 S 5) Tetraarsenic tetrasulfide, As 4 S 4 (2 isomers): the mineral realgar; the mineral pararealgar; Tetraarsenic trisulfide, As 4 S 3, the mineral α- or β- dimorphite