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Others have only peroxide ligands: molybdate reacts in alkaline media with peroxide to form red peroxomolybdate Mo(O 2) 2− 4. [6] The reaction of hydrogen peroxide with aqueous titanium(IV) gives a brightly orange-red colored peroxy complex that is a useful test for titanium as well as hydrogen peroxide. [5]
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Acetone peroxide (/ æ s ə ˈ t ə ʊ n p ɛr ˈ ɒ k s aɪ d / ⓘ also called APEX and mother of Satan [3] [4]) is an organic peroxide and a primary explosive. It is produced by the reaction of acetone and hydrogen peroxide to yield a mixture of linear monomer and cyclic dimer, trimer, and tetramer forms. The monomer is dimethyldioxirane.
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The primary stereoelectronic effect in the Baeyer–Villiger oxidation refers to the necessity of the oxygen-oxygen bond in the peroxide group to be antiperiplanar to the group that migrates. [4] [3] This orientation facilitates optimum overlap of the 𝛔 orbital of the migrating group to the 𝛔* orbital of the peroxide group. [1]
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
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With thousands of tons/year being produced annually, the peroxydisulfates, S 2 O 2− 8, are preeminent members of this class. These salts serve as initiators for polymerization of acrylates and styrene. [1] At one time, sodium perborate was used in detergents.