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For example, the specific rotation of (S)-2-ethyl-2-methyl succinic acid is found to be dependent on concentration; in what is known as the Horeau effect [3] the relationship between mole based ee and optical rotation based ee can be non-linear i.d. in the succinic acid example the optical activity at 50% ee is lower than expected.
While the use of the affix mono-is rarely necessary in organic chemistry, it is often essential in inorganic chemistry to avoid ambiguity: carbon oxide could refer to either carbon monoxide or carbon dioxide. In forming compound affixes, the numeral one is represented by the term hen-except when it forms part of the number eleven (undeca-): hence
Hammond's postulate (or alternatively the Hammond–Leffler postulate), is a hypothesis in physical organic chemistry which describes the geometric structure of the transition state in an organic chemical reaction. [1] First proposed by George Hammond in 1955, the postulate states that: [2]
The solution has 1 mole or 1 equiv Na +, 1 mole or 2 equiv Ca 2+, and 3 mole or 3 equiv Cl −. An earlier definition, used especially for chemical elements , holds that an equivalent is the amount of a substance that will react with 1 g (0.035 oz) of hydrogen , 8 g (0.28 oz) of oxygen , or 35.5 g (1.25 oz) of chlorine —or that will displace ...
The E2 mechanism, where E2 stands for bimolecular elimination, involves a one-step mechanism in which carbon-hydrogen and carbon-halogen bonds break to form a double bond (C=C Pi bond). The specifics of the reaction are as follows: E2 is a single step elimination, with a single transition state.
The number e is a mathematical constant approximately equal to 2.71828 that is the base of the natural logarithm and exponential function.It is sometimes called Euler's number, after the Swiss mathematician Leonhard Euler, though this can invite confusion with Euler numbers, or with Euler's constant, a different constant typically denoted .
A mnemonic is a memory aid used to improve long-term memory and make the process of consolidation easier. Many chemistry aspects, rules, names of compounds, sequences of elements, their reactivity, etc., can be easily and efficiently memorized with the help of mnemonics.
For example: "All humans are mortal, and Socrates is a human. ∴ Socrates is mortal." ∵ Abbreviation of "because" or "since". Placed between two assertions, it means that the first one is implied by the second one. For example: "11 is prime ∵ it has no positive integer factors other than itself and one." ∋ 1. Abbreviation of "such that".