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In industrial chemistry, coal gasification is the process of producing syngas—a mixture consisting primarily of carbon monoxide (CO), hydrogen (H 2), carbon dioxide (CO 2), methane (CH 4), and water vapour (H 2 O)—from coal and water, air and/or oxygen. Historically, coal was gasified to produce coal gas, also known as "town gas".
A catalytic heater is a flameless heater which relies on catalyzed chemical reactions to break down molecules and produce calefaction (heat). [1] When the catalyst, fuel (e.g., natural gas), and oxygen combine together, they react at a low enough temperature that a flame is not produced.
Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N 2), carbon monoxide (CO), hydrogen (H 2), and carbon dioxide (CO 2).
Steam can then be re-injected, then air etc., to give an endless series of cycles until the coke is finally consumed. Producer gas has a much lower energy value, relative to water gas, due primarily to dilution with atmospheric nitrogen. Pure oxygen can be substituted for air to avoid the dilution effect, producing gas of much higher calorific ...
Many gases can be put into a liquid state at normal atmospheric pressure by simple cooling; a few, such as carbon dioxide, require pressurization as well. Liquefaction is used for analyzing the fundamental properties of gas molecules (intermolecular forces), or for the storage of gases, for example: LPG , and in refrigeration and air conditioning .
Theoretically, to make 6 L of water gas, 5 L of air is required. Alternatively, to prevent contamination with nitrogen, energy can be provided by using pure oxygen to burn carbon into carbon monoxide. O 2 + 2 C → 2 CO (ΔH = -221 kJ/mol) In this case, 1 L of oxygen will create 5.3 L of pure water gas.
Carbon monoxide can be produced from CO 2 RR over various precious metal catalysts. [31] Steel has proven to be one such catalyst., [32] or hydrogen. [33] Mechanistically, carbon monoxide arises from the metal bonded to the carbon of CO 2 (see metallacarboxylic acid). Oxygen is lost as water. [34]
Paul Sabatier (1854-1941) winner of the Nobel Prize in Chemistry in 1912 and discoverer of the reaction in 1897. The Sabatier reaction or Sabatier process produces methane and water from a reaction of hydrogen with carbon dioxide at elevated temperatures (optimally 300–400 °C) and pressures (perhaps 3 MPa [1]) in the presence of a nickel catalyst.