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A network solid or covalent network solid (also called atomic crystalline solids or giant covalent structures) [1] [2] is a chemical compound (or element) in which the atoms are bonded by covalent bonds in a continuous network extending throughout the material.
Covalent and ionic bonding form a continuum, with ionic character increasing with increasing difference in the electronegativity of the participating atoms. Covalent bonding corresponds to sharing of a pair of electrons between two atoms of essentially equal electronegativity (for example, C–C and C–H bonds in aliphatic hydrocarbons).
Self-healing materials based on direct photoreversible chemistry in principle don't involve heating. Some examples of this include the systems based on photoreversible cycloaddition that require ultraviolet (UV) irradiation, as well as photo-triggered radical reshufflings of sulfur-based dynamic covalent bonds. [21]
A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs . The stable balance of attractive and repulsive forces between atoms, when they share electrons , is known as covalent bonding. [ 1 ]
IUPAC definition for a crosslink in polymer chemistry. In chemistry and biology, a cross-link is a bond or a short sequence of bonds that links one polymer chain to another. These links may take the form of covalent bonds or ionic bonds and the polymers can be either synthetic polymers or natural polymers (such as proteins).
Molecules that are formed primarily from non-polar covalent bonds are often immiscible in water or other polar solvents, but much more soluble in non-polar solvents such as hexane. A polar covalent bond is a covalent bond with a significant ionic character. This means that the two shared electrons are closer to one of the atoms than the other ...
The bond triangle shows that chemical bonds are not just particular bonds of a specific type. Rather, bond types are interconnected and different compounds have varying degrees of different bonding character (for example, covalent bonds with significant ionic character are called polar covalent bonds).
In organic chemistry, hydrogen bonding is known to facilitate the formation of chain structures. For example, 4-tricyclanol C 10 H 16 O shows catenated hydrogen bonding between the hydroxyl groups, leading to the formation of helical chains; [ 4 ] crystalline isophthalic acid C 8 H 6 O 4 is built up from molecules connected by hydrogen bonds ...