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Trimethyl phosphate is prepared by treating phosphorus oxychloride with methanol in the presence of an amine base: POCl 3 + 3 CH 3 OH + 3 R 3 N → PO(OCH 3) 3 + 3 R 3 NH + Cl −. It is a tetrahedral molecule that is a weakly polar solvent.
Trimethyl phosphite is an organophosphorus compound with the formula P(OCH 3) 3, often abbreviated P(OMe) 3.It is a colorless liquid with a highly pungent odor. It is the simplest phosphite ester and finds used as a ligand in organometallic chemistry and as a reagent in organic synthesis.
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Phosphorus that runs into freshwater lakes and rivers can cause algal blooms. [16] [19] Phosphate-free detergent reduces the amount of phosphate that wastewater treatment plants must clean up. [16] From the 1960s-2010s the standard way to determine the amount of phosphate in water has been using colorimetry. [20]
Phosphite esters are typically prepared by treating phosphorus trichloride with an alcohol. For alkyl alcohols the displaced chloride ion can attack the phosphite, causing dealkylation to give a dialkylphosphite and an organochlorine compound. [1] [2] The overall reaction is as follows: PCl 3 + 3 C 2 H 5 OH → (C 2 H 5 O) 2 P(O)H + 2 HCl + C 2 ...
Trimethylphosphine is a highly basic ligand that forms complexes with most metals. As a ligand, trimethylphosphine's Tolman cone angle is 118°. [7] This angle is an indication of the amount of steric protection that this ligand provides to the metal that to which it is bound.
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