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Vaporization (or vapo(u)risation) of an element or compound is a phase transition from the liquid phase to vapor. [1] There are two types of vaporization: evaporation and boiling . Evaporation is a surface phenomenon , whereas boiling is a bulk phenomenon (a phenomenon in which the whole object or substance is involved in the process).
The increase in the internal energy can be viewed as the energy required to overcome the intermolecular interactions in the liquid (or solid, in the case of sublimation). Hence helium has a particularly low enthalpy of vaporization, 0.0845 kJ/mol, as the van der Waals forces between helium atoms are particularly weak.
Boiling is the method of cooking food in boiling water or other water-based liquids such as stock or milk. [13] Simmering is gentle boiling, while in poaching the cooking liquid moves but scarcely bubbles. [14] The boiling point of water is typically considered to be 100 °C (212 °F; 373 K), especially at sea level.
For example, when water evaporates, an input of energy is required for the water molecules to overcome the forces of attraction between them and make the transition from water to vapor. If the vapor then condenses to a liquid on a surface, then the vapor's latent energy absorbed during evaporation is released as the liquid's sensible heat onto ...
Water vapor is the "working medium" of the atmospheric thermodynamic engine which transforms heat energy from sun irradiation into mechanical energy in the form of winds. Transforming thermal energy into mechanical energy requires an upper and a lower temperature level, as well as a working medium which shuttles forth and back between both.
In thermodynamics, Trouton's rule states that the (molar) entropy of vaporization is almost the same value, about 85–88 J/(K·mol), for various kinds of liquids at their boiling points. [1] The entropy of vaporization is defined as the ratio between the enthalpy of vaporization and the boiling temperature.
Since the kinetic energy of a molecule is proportional to its temperature, evaporation proceeds more quickly at higher temperatures. As the faster-moving molecules escape, the remaining molecules have lower average kinetic energy, and the temperature of the liquid decreases. This phenomenon is also called evaporative cooling.
The standard boiling point has been defined by IUPAC since 1982 as the temperature at which boiling occurs under a pressure of one bar. [6] The heat of vaporization is the energy required to transform a given quantity (a mol, kg, pound, etc.) of a substance from a liquid into a gas at a given pressure (often atmospheric pressure).