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Electron ionization. Electron ionization (EI, formerly known as electron impact ionization [1] and electron bombardment ionization [2]) is an ionization method in which energetic electrons interact with solid or gas phase atoms or molecules to produce ions. [3] EI was one of the first ionization techniques developed for mass spectrometry. [4]
Adiabatic ionization is a form of ionization in which an electron is removed from or added to an atom or molecule in its lowest energy state to form an ion in its lowest energy state. [ 16 ] The Townsend discharge is a good example of the creation of positive ions and free electrons due to ion impact.
[1] This is the minimum electron energy that produces an ion. [2] In photoionization, it is the minimum photon energy of a photon that produces some ion signal. For example, the indene bromide ion (IndBr+) only loses bromine at an incident photon energy of 10.2 eV, so the product, indenyl, has an appearance energy of 10.2 eV. [3]
A certain amount of energy, which may be large enough, is required to remove an electron from an atom or a molecule in its ground state. [12] [13] In chemi-ionization processes, the energy consumed by the ionization must be stored in atoms or molecules in a form of potencial energy or can be obtained from an accompanying exothermic chemical change (for example, from a formation of a new ...
Electron capture ionization (ECI) is the ionization of a gas phase atom or molecule by attachment of an electron to create an ion of the form A −•.The reaction is + where the M over the arrow denotes that to conserve energy and momentum a third body is required (the molecularity of the reaction is three).
The first of these quantities is used in atomic physics, the second in chemistry, but both refer to the same basic property of the element. To convert from "value of ionization energy" to the corresponding "value of molar ionization energy", the conversion is: 1 eV = 96.48534 kJ/mol 1 kJ/mol = 0.0103642688 eV [12]
Resonance electron capture [3] is also known as nondissociative EC. The compound captures an electron to form a radical anion. [4] The energy of the electrons are about 0 eV. The electrons can be created in the Electron Ionization source with moderating gas such as H 2, CH 4, i-C 4 H 10, NH 3, N 2, and Ar. [5] After the ion captures the electron, the complex formed can stabilize during ...
Electron ionization allows the observation of some states which cannot be excited by photons due to selection rules. In neon for example again, the excitation of triplet states is forbidden by the spin selection rule ΔS = 0, but the 1s 2 2s 2 2p 4 3s 3p ( 3 P) has been observed by electron ionization at 42.04 eV. [ 3 ]